专家信息:
王勇,男,1979年出生于湖南汨罗,博士生导师。现任浙江大学求是特聘教授,博士生导师,催化研究所所长。国家重点研发计划项目首席科学家,中组部“万人计划”青年拔尖人才、国家优秀青年基金及杰出青年基金获得者。2002年本科毕业于湘潭大学化工学院,2007年博士毕业于浙江大学化工系,2007年~2009年在浙江大学化学系从事博士后研究工作,2009年~2011年在德国马普胶体与界面化学研究所从事博士后研究工作,2011年进入浙江大学工作至今。荣获第九届中国催化青年奖、侯德榜化工科技-创新奖等荣誉。作为项目负责人先后承担多项国家及省部级项目,如国家自然科学基金优秀青年基金、面上项目以及浙江省杰出青年基金和重点基金等项目。王勇课题组致力于工业催化剂的研发,特别是基于多孔炭及金属氧化物的负载型工业催化剂的开发及相关反应机理的研究,所研发的多个催化剂在工业上得到应用, 产生了显著的经济和社会效益。在Chem., J. Am. Chem. Soc., Nat. Commun., Angew. Chem. Int. Ed.等期刊上发表SCI论文170余篇,被引用2.3万余次,H-index 66。获授权国家发明专利40余件。入选“高被引学者”名单,研究成果荣获中国专利金奖、中国石油与化学工业联合会“发明特等奖”、浙江省科学技术奖-技术发明一等奖以及浙江省自然科学一等奖等荣誉。
教育及工作经历:
2002年本科毕业于湘潭大学。
2007年博士毕业于浙江大学化工系,获工学博士学位,博士论文被评为浙江省优秀博士论文以及全国百篇优秀博士论文提名奖论文。
2007年~2009年在浙江大学化学系从事博士后研究工作,合作导师李浩然教授,并荣获“浙江省优秀博士后”称号。
2009年4月~2011年3月在德国马普胶体与界面化学研究所从事博士后研究工作,合作导师Markus Antonietti教授。
2011年4月起回国担任浙江大学化学系特聘研究员。
学术兼职:
1、担任国际期刊Scientific Reports的编委。
主讲课程
资料更新中……
培养研究生情况:
在读博士生12名,在读硕士生7名,毕业博士生2名。
招生信息:
1. 欢迎本科生同学来课题组开展科研实验或做毕业设计;
2. 课题组每年招收博士研究生3名,硕士研究生2名;
3.课题组招收博士后多名,欢迎具有多相催化、电催化、材料、有机及理论计算等背景的博士来课题组从事博士后研究工作(待遇面议)。
研究方向:
Professor Wang’s advanced materials and catalysis research group has been focusing its efforts on the basic science and applied research for the design and development of heterogeneous catalysis, energy storage, and energy conversion carbon based materials. They strive to pursue green energy technologies and the beautiful fundamental science that make these technologies a reality.
(i) The use of biomass as renewable raw materials conforms to the conception of Green Chemistry. Besides the sustainability of the bio-carbon, the conversion of biomass to functional materials provided an effective route to add to the value of fabricated products. We focus on exploring the novel and green methods to synthesize carbon materials with controllable morphology, porous structure, and functional surface on the basis of biomass and derivatives.
Selected Publications:
(1) Chen, C. H.; Mao, S. J.; Tan, C. L.*; Wang, Z.; Ge, Y. Y.; Ma, Q. L.; Zhang, X.; Qi, G. D.; Xu, J.; Fan, Z. X.; Wang, Y*. General synthesis of ordered mesoporous carbonaceous hybrid nanostructures with molecularly dispersed polyoxometallates, Angew. Chem. Int. Ed., 2021, 60, 15556-15562.
(2) Liu, J. R.; Xie, L.; Deng, J.; Gong, Y. T.; Tang, G. P.; Bai, H. Z.*, Wang, Y.* Annular mesoporous carbonaceous nanospheres from biomass-derived building units with enhanced biological interactions, Chem. Mater., 2019, 31, 7186-7191.
(3) Chen, C. H.; Wang, H. Y.; Han, C. L.; Deng, J.; Wang, J.; Li, M. M.; Tang, M. H. Jin, H. Y.; Wang, Y.*, Asymmetric flask-like hollow carbonaceous nanoparticles fabricated by the synergistic interaction between soft template and biomass. J. Am. Chem. Soc., 2017, 139, 2657-2663.
(4) Deng, J.; Xiong, T. Y.; Xu, F.; Li, M. M.; Han, C. L.; Gong, Y. T.; Wang, H. Y.; Wang, Y.* Inspired by bread leavening: One-pot synthesis of hierarchically porous carbon for supercapacitors. Green Chem., 2015, 7, 4053-4060.
(5) Zhang, P. F.; Yuan, J. Y.*; Tim-Patrick,F.; Antonietti, M.; Li, H. R.; Wang, Y.* Improving hydrothermal carbonization by poly(ionic liquid)s. Angew. Chem. Int. Ed., 2013, 52, 6028-6032.
(ii) We are also committed to developed N-doped carbon based composites supported metal and non-noble metal as low-cost and highly efficient catalysts. Moreover, the mechanisms of reactions have been investigated both experimentally and with density functional theory (DFT) modeling. To be sure, the synthesis strategy provides a versatile platform to introduce various metal species on nitrogen-doped carbon with targeted and improved properties for diverse catalytic reactions.
Selected Publications:
(1) Ning, H. H.; Chen, Y. Z.; Wang, Z. Z.; Mao, S. J.*; Chen, Z. R.; Gong, Y. T.; Wang, Y.* Selective upgrading of biomass-derived benzylic ketones by (formic acid)-Pd/HPC-NH2 system with high efficiency under ambient conditions, Chem, 2021, 7,3069-3084.
(2) Wang, Z. Z.; Liang, S. P.; Meng, X. Y.; Mao, S. J.*; Lian, X.; Wang, Y.* Ultrasmall PdAu alloy nanoparticles anchored on amine-functionalized hierarchically porous carbon as additive-free catalysts for highly efficient dehydrogenation of formic acid. Appl. Catal. B Environ., 2021, 291, 120140.
(3) Wang, C. P.; Mao, S. J.*; Wang, Z.; Chen, Y. Z.; Yuan, W. T.; Ou Y.; Zhang, H.; Gong, Y. T.; Wang, Y.; Mei, B. B.; Jiang, Z.; Wang, Y.* Insight into Single-atom Induced Unconventional Size-dependence over CeO2-supported Pt Catalysts, Chem., 2020, 6, 752-765.
(4) Mao, S. J.; Wang, C. P.; Wang, Y.* The chemical nature of N doping on N doped carbon supported noble metal catalysts. J. Catal., 2019, 375, 456-465.
(5) Xu, X.; Li, Y.; Gong, Y. T.; Zhang, P. F.; Li, H. R.; Wang, Y.* Synthesis of palladium nanoparticles supported on mesoporous N-doped carbon and their catalytic ability for biofuel upgrade. J. Am. Chem. Soc., 2012, 134, 16987-16990.
(iii) As growing demand for energy in the future, energy conversion and storage are of great interest in our research group. Due to green chemistry, electric energy gained hot research concentration and will experience fast growth. Thus, electrical catalysts for energy conversion are our focused highlights.
Selected Publications:
(1) Chen, J. D.; Qin, M. K.; Ma, S. X.; Fan, R. X.; Zheng, X. Z.; Mao, S. J.; Chen, C. H.; Wang, Y*. Rational construction of Pt/PtTex interface with optimal intermediate adsorption energy for efficient hydrogen evolution reaction, Appl. Catal. B Environ., 2021, 299, 120640.
(2) Wang, J.; Wei, Z. Z.; Mao, S. J.; Li, H. R.; Wang, Y.*, Highly uniform Ru nanoparticles over N-doped carbon: pH and temperature-universal hydrogen release from water reduction, Energ. Environ. Sci., 2018, 11, 800-806.
(3 Wang, J.; Xu, F.; Jin, H. Y.; Chen, Y. Q.; Wang, Y.*, Non-noble metal-based carbon composites in hydrogen evolution reaction: fundamentals to applications, Adv. Mater., 2017, 29, 1605838.
(4) Wang, S. P.; Wang, J.; Zhu, M. L.; Bao, X. B.; Xiao, B. Y.; Su, D. F.; Li, H. R.; Wang, Y.* Molybdenum carbide-modified nitrogen-doped carbon vesicle encap-sulating nickel nanoparticles: A highly efficient, low-cost catalyst for hydrogen evolution reaction. J. Am. Chem. Soc., 2015, 137, 15753-15759.
(5) Jin, H. Y.; Wang, J.; Su, D. F.; Wei, Z. Z.; Pang, Z. F.; Wang, Y.* In-situ cobalt-cobalt oxide/N-doped carbon hybrids as superior bi-functional electrocatalysts for hydrogen and oxygen evolution. J. Am. Chem. Soc., 2015, 137, 2688.
承担科研项目情况:
作为项目负责人承担多项国家自然科学基金、浙江省杰出青年基金及教育部博士点基金等。
1. 国家自然科学基金杰出青年基金,22325204,负载型纳米金属催化剂及应用 ,2024/01-2027/12,在研,负责人:王勇。
2. 浙江省“尖兵”研发攻关计划项目,2023C01108, 高端香料二氢茉莉酮酸甲酯的精准合成及产业化, 2022/09-2025/09,在研,负责人:王勇。
3. 科技部国家重点研发计划项目,2021YFB3801600,重要反应过程贵金属等效减量的关键技术开发及应用示范,2021/12-2024/11, 在研,首席科学家:王勇。
4. 浙江省“领雁”研发攻关计划项目,2022C01151,高效电催化二氧化碳还原催化剂的开发及示范化应用,2021/09-2024/08,在研,负责人:杨瑞。
5. 浙江省“领雁”研发攻关计划项目,2022C01218,高性能催化材料开发及应用-高效多相羰基化催化剂的开发以及应用,2021/09-2024/06,在研,负责人:毛善俊。
6. 企业横向经费,202133000400,强力霉素氢化工艺改进项目,2021/06-2022/06, 结题,负责人:王勇。
7. 企业横向经费,环己醇脱氢制备环己酮高效催化剂开发,2021/04-2022/09, 结题,负责人:王勇。
8. 企业横向经费,K横20201745,高性能纳米金属催化剂研制及应用,2020/01-2025/12,在研,负责人:王勇。
9. 浙江省重点研发计划项目,2020C01133,高性能加氢催化剂的精准合成及产业化应用研究,2019/09-2022/08,结题,负责人:毛善俊。
10. 国家自然科学基金青年项目,21908189,卤代芳胺合成中的关键脱卤因素研究以及高效催化剂设计,2020/01-2022/12,结题,负责人:毛善俊。
11. 国家自然科学基金面上项目,21872121,炔醇加氢机理研究及高效催化剂的开发,2019/01-2022/12,结题,负责人:王勇。
12. 国家自然科学基金青年项目,21802120,三元金属间化合物负载Ru催化剂的设计合成及其合成氨催化性能研究,2019/01-2021/12,结题,负责人:巩玉同。
13. 浙江省自然科学基金重点项目,LZ18B060002,维生素E产业链中关键中间体高性能加氢催化剂的开发,2018/01-2021/12,提前结题,负责人:王勇。
14. 国家自然科学基金优秀青年基金项目,21622308,炭材料与多相催化,2017/01-2019/12,结题,负责人:王勇。
15. 国家重点研发专项子课题,2016YFA0202900,微纳结构有机分子催化材料,2016/07-2021/06,结题,负责人:王勇。
16. 中组部万人计划“青年拔尖人才”项目,2016/01-2018/12,结题,负责人:王勇。
17. 国家自然科学基金重大研究计划项目培育项目,91534114,芳环加氢炭负载型多相催化剂的多尺度设计及研制,2016/01-2018/12,结题,负责人:王勇。
18. 国家自然科学基金面上项目,21376208,用于取代硝基化合物选择性加氢反应的纳米催化剂研制、2014/01-2017/12,结题,负责人:王勇。
19. 浙江省自然科学基金杰出青年基金,LR13B030001,基于碳氮材料纳米催化剂的制备及应用研究、LR13B03001,2013/01-2016/12,结题,负责人:王勇。
20. 浙江大学-马普胶体与界面化学研究所伙伴计划,碳基纳米催化剂及其在生物质转化中的应用,2011/11-2016/11,结题,负责人:王勇。
21. 企业横向经费,H20150385,苯酚气相加氢制备环己酮催化剂开发,2015/01-2018/12,在研,负责人:王勇。
22. 教育部博士点基金-博导类,J20130060,多孔氮化碳负载的纳米金属催化剂及其在喹啉选择性加氢反应中的应用,2013/01-2015/12,结题,负责人:王勇。
23. 国家自然科学基金石油化工联合基金培育项目,U1162124,基于三维介孔氮化碳的多功能催化剂的设计与研制,2012/01-2014/12,结题,负责人:王勇。
24. 企业横向经费,H20112656,苯酚加氢制备环己酮技术,2011/09-2015/09,结题,负责人:王勇。
25 .国家自然科学基金-青年科学基金,20806065,结合谱学和理论计算研究质子型离子液体的微观结构,2009/01-2011/12,结题,负责人:王勇。
科研成果:
1.迄今已在Nat. Commun.,J. Am. Chem. Soc.; Angew. Chem. Int. Ed.; Chem. Mater.; J. Catal.等国际知名刊物上发表科研论文100余篇,H因子26。
发明专利:
1. 王勇,郑晓忠,杨瑞,陆冰,罗乾,刘彦玲,氧化钒负载型高分散且结构畸变的纳米簇催化剂及其制备方法和应用,ZL 202210019482.X
2. 王勇,王珍珍,毛善俊,梁世潘,一种高比表面积金属氧化物及其制备方法和应用,ZL 202110894884.X
3. 王勇,陆冰,毛善俊,王哲, 一种用于碳碳偶联反应的酸碱双位点催化剂及其应用, ZL 202111213624.8.
4. 王勇,陆冰,陈春红,毛善俊,单分子杂多酸镶嵌的蜂窝状炭材料负载的纳米金属催化剂及其制备方法和应用,ZL 202010107709.7
5. 王勇,陈宇卓,罗乾,毛善俊,一种负载型催化剂及其制备方法和应用,ZL201911084810.9
6. 王勇,陈春红,陆冰,毛善俊,一种多孔炭负载型单分子杂多酸催化剂及其制备方法和应用,ZL202010108012.1
7. 李浩然,王勇,胡柏剡,马啸,仇丹,罗乾,王哲,毛善俊,于丽丽,李其川,一种选择性加氢催化剂及其制备方法和应用,ZL 202010102438.6
8. 王勇;刘锦蓉;谢磊;邓江;巩玉同,一种类齿轮状介孔炭纳米球材料、制备方法及应用, ZL201910039858.1
9. 王勇;巩玉同;王哲;毛善俊;陈佳东;李浩然,一种高分散负载型催化剂及其制备方法和应用,ZL201910451496.7
10. 王勇,方忠锋,一种醋酸乙酯加氢制乙醇的催化剂及其制备方法和应用,ZL 201810175970.3
11. 王勇,王哲,毛善俊,巩玉同,宁红辉,陈佳东,一种选择性加氢催化剂在加氢反应中作为催化剂的应用,ZL201910452579.8
12. 王勇,陈益庆,曹月领,王哲,一种高分散纳米金属氧化物复合的炭材料及其制备方法和应用,ZL201810765050.7
13. 王勇,孔祥千,毛善俊,王春鹏,陈宇卓,一种高分散纳米催化剂的制备方法,ZL201711228648.4.
14. 王勇;陈佳东,单分散的金属-单宁酸包覆活化碳布的催化剂及其制备方法和应用, ZL201910211520.X
15. 王勇,毛善俊,王哲,一种氮掺杂多级孔炭负载的纳米Pd催化剂的制备方法及其产品和应用,ZL201911028624.3
16. 王勇,王哲,毛善俊,陈益庆,赵博文,炔醇选择性加氢催化剂及其制备方法和应用,ZL201811043834.5
17. 王勇;邓江;王海燕,一种柔性锂离子电容器用负极材料及其制备方法和应用,ZL201711237123.7
18. 王勇,陈佳熠,王哲,王海燕,一种高效分散钼基催化剂的制备方法及其应用,ZL201910125706.3
19. 王勇,马啸,于丽丽,王哲,毛善俊,李建清,陈钢,李浩然,陈志荣,PdIn合金催化剂及其制备方法、应用,ZL201811010568.6
20. 王勇,吕国锋,于丽丽,王哲,毛善俊,唐静思,李浩然,陈志荣,复合催化剂及其制备方法、应用,ZL201811010567.1
21. 王勇,王海燕,一种二氧化锰/超微孔柔性碳布的制备方法、产品及应用,ZL201611191041.9.
22. 王勇, 谢磊, 贝壳状超结构炭材料的制备方法及产品, ZL 2017106646209.
23. 王勇,李名明,邓江,氮掺杂多级孔炭及其制备方法和应用,ZL 201610492985.3.
24. 王勇,于丽丽,李建清,陈钢,李名明,沈凌峰,张玉霞,陈志荣,李浩然,王柳枫,陶娟娟,一种用于炔醇选择性加氢的催化剂及其制备方法和应用,ZL201610707572.2
25. 王勇,王静,魏中哲,王海燕,3D多孔电极的制备方法及其在电化学析氢反应中的应用,ZL 201610640590.3
26. 王勇,陈春红,韩传龙,邓江,中空炭材料的制备方法及其产品,ZL 2016 1 0388548.7
27. 王勇,鲍晓冰,巩玉同,一种Fe-N-C氧还原催化剂及其合成方法和应用,ZL 201610288312.6
28. 王勇,邓江,李建清,汤明慧,李名明,一种利用回收废炭制备含氮多孔炭的方法及其产品和应用,ZL 201610487519.6
29. 王勇,王静,魏中哲,李浩然,王世萍,韩传龙,一种基于碳管与过渡金属复合的催化剂制备烯烃类化合物的方法,ZL 2015 1 0026459.3
30. 王勇,王海燕,一种制备超微孔碳布的方法及其产品和应用,ZL 201610107519.9
31. 王柳枫 徐志超 李建清 王勇 李浩然 陈志荣,一种生物素中间体加氢钯炭催化剂的再活化方法,ZL201611228094.3
32. 王勇,王海燕,一种锰的氧化物/多孔炭纳米纤维复合材料的制备方法及其产品和应用,ZL 2014 1 0727218.7
33. 王勇,邓江,熊天一,苏叠峰, 徐凡,一种多级孔碳材料的制备方法及产品,ZL 2014 1 0796050.5
34. 王勇,王世萍,韩传龙,王静,朱明蕾,表面功能化的有序介孔掺氮炭材料的制备方法,ZL 2014 1 0309930.5
35. 王勇,魏中哲,王静,一种用于芳硝基化合物选择性加氢反应的多相催化剂及其应用,ZL201410389748.5
36. 王勇,邓江,熊天一,巩玉同,徐凡,一种纳米级层状二氧化硅/石墨烯复合材料的制备方法及其产品,ZL201410797490.2
37. 王勇,王世萍,韩传龙,王世国,王静,肖冰洋,一种掺氮碳纳米管的制备方法及其产品,ZL201410401402.2
38. 王勇,王静,巩玉同,王世萍,韩传龙,一种大管径、超长纳米碳管的制备方法,ZL201410338644.1
39. 王勇,张鹏飞,一种基于离子热过程的多孔炭材料制备方法,ZL201310328455.1
40. 王勇,巩玉同,一种多孔碳的制备方法及其产品,ZL201410038705.2
41. 王勇,徐旋,芳香化合物催化加氢制备环己基化合物的方法,ZL201310012978.5
42. 王勇,徐旋,巩玉同,李浩然,一种新型介孔碳担载的金属催化剂及其制备方法,ZL201110387825.X
43. 王勇,巩玉同,李浩然,一种苯甲醛类化合物的制备方法及其用新型介孔碳担载的双金属催化剂,ZL201110387822.6
44. 王勇,张鹏飞,一种小尺寸实心碳球的制备方法及制备得到的碳球,ZL201210562902.5
45. 王勇,张鹏飞,李浩然,一种硫化物的选择性氧化方法,ZL201110390268.7
46. 王勇,徐旋,李翼,李浩然,一种芳香族硝基化合物选择性加氢还原方法,ZL201110389173.3
在Nature Commun., J. Am. Chem. Soc.; Angew. Chem. Int. Ed.; Chem. Commun.; Chem. Mater.; J. Catal. 等国际知名刊物上累积发表论文70余篇,被引2300多次,h-index 26。
发表英文论文
2024年
1. Jinqi Xiong, Shanjun Mao*, Qian Luo, Honghui Ning, Bing Lu, Yanling Liu and Yong Wang*, Mediating trade-off between activity and selectivity in alkynes semi-hydrogenation via a hydrophilic polar layer, Nat. Commun., 2024, 15, 1228.
2. Zhe Wang, Chunpeng Wang, Bing Lu, Zhirong Chen, Yong Wang*, Shanjun Mao*, Electronic perturbation-promoted interfacial pathway for facile C-H dissociation, Chin. J. Catal., 2024, 56, 130-138.
2023年
1. Honghui Ning, Xiaozhong Zheng, Jinqi Xiong, Bing Lu, Yong Wang, Kaichao Zhang, and Shanjun Mao*, Rebalancing Hydrogenation and Dehydration Performances for Efficient Hydrodeoxygenation of Biomass Derivatives to Match Reaction Temperature-Induced Rate-Determining Step Switch, Ind. Eng. Chem. Res., 2023, 62, 44, 18403–18415
2. Xiaotong Li, Minkai Qin, Xiuju Wu, Xiangzhou Lv, Jianghao Wang, Yong Wang*, Hao Bin Wu*, Enhanced CO Affinity on Cu Facilitates CO2 Electroreduction toward Multi-Carbon Products, Small, 2023, 2302530.
3. Xiaoyun Shi†, Xiaozhong Zheng†, Hao Wang, Hao Zhang, Minkai Qin, Binbin Lin, Menghui Qi, Shanjun Mao, Honghui Ning, Rui Yang, Lingling Xi*, Yong Wang*, Hierarchical Crystalline/Amorphous Heterostructure MoNi/NiMoOx for Electrochemical Hydrogen Evolution with Industry-Level Activity and Stability,Adv. Funct. Mater., 2023, 2307109.
4. 毛善俊、王哲、王勇*,“基团辨识加氢”:从概念到应用,《化工进展》, 2023, 42, 3917-3922.
5. Xiaozhong Zheng, Xiaoyun Shi, Honghui Ning, Rui Yang, Bing Lu, Qian Luo, Shanjun Mao, Lingling Xi, Yong Wang*, Tailoring a local acid-like microenvironment for efficient neutral hydrogen evolution, Nat. Commun., 2023, 14, 4209.
6. Minkai Qina, Menghui Qia, Ruxue Fan, Jiadong Chena, Xiaoyun Shi, Binbin Lin, Lingling Xi, Yong Wang*, K Intercalation-assisted Co-doped MoS2 Nanoflowers for Efficient Hydrogen Evolution Reaction, Precis. Chem., 2023, doi.org/10.1021/prechem.3c00033.
7. Liwei Zhang, Shanjun Mao,* Yali Liu, Bing Lu, Yongtao Wang, Haoran Li* and Yong Wang* Tandem Catalytic Efficient Olefin Epoxidation with Integrated Production of Nicotinamide Derivatives, Chem Catal., 2023, 3, 100691.
8. Yuzhuo Chen, Hao Wang, Bing Lu, Ni Yi, Liang Cao, Yong Wang, Shanjun Mao*, Fine-structure sensitive deep learning framework for prediction of catalytic properties with high precision,Chin. J. Catal., 2023, 50, 284-296.
9. Lihua Wang, Shuangxiu Ma, Chunhong Chen, Bing Lu, Zhe Wang, Yong Wang, and Shanjun Mao*, Pentacoordinated Al3+ stabilized polyoxometalates for the efficient catalytic valorization of biomass-derived feedstocks, Catal. Sci. Technol., 2023, 13, 3558-3567.
10. Bing Lu, Shuangxiu Ma, Shipan Liang, Zhe Wang, Yali Liu, Shanjun Mao, Heng Ban, Lihua Wang, Yong Wang,* Efficient conversion of ethanol to 1-butanol over adjacent acid-base dual sites via enhanced C-H activation, ACS Catal., 2023, 13, 4866-4872.
11. Mao, Shanjun; Wang, Zhe; Luo, Qian; Lu, Bing; Wang, Yong*, Geometric and electronic effects in hydrogenation reactions, ACS Catal., 2023, 13, 974-1019.
12. Yutong Gong, Lei Xie, Chunhong Chen, Jinrong Liu, Markus Antonietti*, Yong Wang*, Bottom-up Hydrothermal Carbonization for the Precise Engineering of Carbon Materials, Prog. Mater. Sci., 2023, 132, 101048.
2022年
1. Jiadong Chen, Chunhong Chen, Minkai Qin, Ben Li, Binbin Lin, Qing Mao, Hongbin Yang, Bin Liu*, Yong Wang*, Reversible hydrogen spillover in Ru-WO3-x enhances hydrogen evolution activity in neutral pH water splitting, Nat. Commun., 2022, 13, 5382.
2. Binbin Lin†, Jiadong Chen†, Rui Yang, Shanjun Mao, Minkai Qin, Yong Wang*, Multi-hierarchical cobalt-based electrocatalyst towards high rate H2 production, Appl. Catal. B Environ., 2022, 316, 121666.
3. Zhe Wang#, Chunpeng Wang#, Shanjun Mao*, Bing Lu, Yuzhuo Chen, Xie Zhang, Zhirong Chen, Yong Wang*, Decoupling the Electronic and Geometric Effects of Pt Catalysts in Selective Hydrogenation Reaction, Nat. Commun., 2022, 13, 3561.
4. Minkai Qin, Jiadong Chen, Xiaozhong Zheng, Menghui Qi, Rui Yang, Shanjun Mao, Yong Wang*, Operando deciphering the activity origins for potential-induced reconstructed oxygen-evolving catalysts, Appl. Catal. B Environ., 2022, 316, 121602.
5. Zhe Wang, Qian Luo, Shanjun Mao, Chunpeng Wang, Jinqi Xiong, Zhirong Chen, Yong Wang*, Fundamental aspects of alkyne semi-hydrogenation over heterogeneous catalysts, Nano Res., 2022, 15, 10044–10062.
6. Ruxue Fan, Haiyan Wang, Xiaozhong Zheng, Jiadong Chen, Yang Ou, Yong Wang, Shanjun Mao*, Fe2 Dimers for Non-Polar Diatomic O2 Electroreduction, ChemSusChem, 2022, 15, e202200532.
7. Xie Zhang, Chunhong Chen*, Chenyang Tang, Yong Wang*, Morphological Control of Biochar with Emerging Functionalities by Thermodynamic and Kinetic Approaches, Acc. Mater. Res., 2022, 3, 525-539.
8. Rui Yang, Xiaozhong Zheng, Minkai Qin, Binbin Lin, Xiaoyun Shi, Yong Wang*, A trifunctional Ni-P/Fe-P collaborated electrocatalyst enables self-powered energy systems, Adv. Sci., 2022, 2201594.
9. Minkai Qin, Ruxue Fan, Jiadong Chen, Haiyan Wang, Xiaozhong Zheng, Shanjun Mao, Renfeng Du, Yong Wang*, Elucidating electrocatalytic mechanism for large-scale cycloalkanol oxidation integrated with hydrogen evolution, Chem. Eng. J., 2022, 442, 136264.
10. Xiaozhong Zheng, Minkai Qin, Shuangxiu Ma, Yuzhuo Chen, Honghui Ning, Rui Yang, Shanjun Mao, and Yong Wang*, Strong Oxide-Support Interaction over IrO2/V2O5 for Efficient pH-Universal Water Splitting, Adv. Sci., 2022, 2104636.
11. Lei Xie, Jinrong Liu, Xiaobing Bao, Jiadong Chen, Xiaozhong Zheng, Yanjun He, Wei Zhang, Jie Zeng, Yong Wang*, Biao Kong*, Interfacial Assembly of Nanowire Arrays toward Carbonaceous Mesoporous Nanorods and Superstructures, Small, 2022, 18, 2104477.
12. Chunpeng Wang#, Zhe Wang#, Shanjun Mao, Zhirong Chen, Yong Wang*, Coordination Environment of Active Sites and Their Effect on Catalytic Performance of Heterogeneous Catalysts, Chin. J. Catal., 2022, 43, 928-955.
2021年
1. Bing Lu, Zhe Wang, Shuangxiu Ma, Shanjun Mao, Zhirong Chen, and Yong Wang*, Spatial Charge Separation Induced New Mechanism of Efficient C-C Coupling by Forming Ion-Pair Intermediates, Chem Catal., 2021, 1, 1449-1465.
2. Chunhong Chen, Yong Wang*, The precise engineering of nanostructured carbon materials, ACS Cent. Sci., 2021, 7, 1470-1472.(First Reactions)
3. Jiadong Chen, Minkai Qin, Shuangxiu Ma, Ruxue Fan, Xiaozhong Zheng, Shanjun Mao, Chunhong Chen and Yong Wang* Rational Construction of Pt/PtTex Interface with Optimal Intermediate Adsorption Energy for Efficient Hydrogen Evolution Reaction, Appl. Catal. B Environ., 2021, 299, 120640.
4. Honghui Ning, Yuzhuo Chen, Zhenzhen Wang, Shanjun Mao,*, Zhirong Chen, Yutong Gong and Yong Wang*, Selective Upgrading of Biomass-derived Benzylic Ketones by (Formic Acid)-Pd/HPC-NH2 System with High Efficiency under Ambient Conditions, Chem, 2021, 7,3069-3084.
5. Qian Luo,†,# Zhe Wang,†,# Yuzhuo Chen,† Shanjun Mao,*,† Kejun Wu,‡ Kaichao Zhang,‡ Qichuan Li,‡ Guofeng Lv,‡ Guodong Huang,‡ Haoran Li,† and Yong Wang*,† Dynamic Modification of Palladium Catalysts with Chain Alkylamines for the Selective Hydrogenation of Alkynes, ACS Appl. Mater. & Inter., 2021, 13, 31775-31784.
6. Chunhong Chen, Shanjun Mao, Chaoliang Tan,* Zhe Wang, Yiyao Ge, Qinglang Ma, Xiao Zhang, Guodong Qi, Jun Xu, Zhanxi Fan, and Yong Wang*, General Synthesis of Ordered Mesoporous Carbonaceous Hybrid Nanostructures with Molecularly Dispersed Polyoxometallates, Angew. Chem. Int. Ed.,2021, 60, 15556-15562.
7. Lei Xie, Shan Zhou, Jinrong Liu, Beilei Qiu, Tianyi Liu, Qirui Liang, Xiaozhong Zheng, Ben Li, Jie Zeng, Miao Yan, Yanjun He, Xin Zhang, Hui Zeng, Ding Ma, Pu Chen, Kang Liang, Lei Jiang, Yong Wang*, Dongyuan Zhao*, and Biao Kong*, Sequential Superassembly of Nanofiber Arrays to Carbonaceous Ordered Mesoporous Nanowires and Their Heterostructure Membranes for Osmotic Energy Conversion,J. Am. Chem. Soc. 2021, 143, 6922-6932.
8. Zhenzhen Wang, Shipan Liang, Xiaoyan Meng, Shanjun Mao*, Xu Lian, and Yong Wang*, Ultrasmall PdAu Alloy Nanoparticles Anchored on Amine-functionalized Hierarchically Porous Carbon as Additive-free Catalysts for Highly Efficient Dehydrogenation of Formic Acid. Appl. Catal. B Environ., 2021, 291, 120140.
2020年
1. Shanjun Mao1, Zhe Wang1, Zhirong Chen2, Kejun Wu3, Kaichao Zhang3, Qichuan Li3, Huihuan Yan3, Guofeng Lü3, Guodong Huang3, and Yong Wang1*, Towards the selectivity distinction of phenol hydrogenation on noble metal catalysts, Nano Mater. Sci., 2023, 5, 91-100.
2. Jiadong Chen,# Chunhong Chen,# Yuzhuo Chen, Haiyan Wang, Shanjun Mao, and Yong Wang*, Improving Alkaline Hydrogen Evolution Reaction Kinetics on Molybdenum Carbide: Introducing Ru dopant. J. Catal., 2020, 392, 313-321.
3. Xiaozhong Zheng, Yuzhuo Chen, Xiaobing Bao, Shanjun Mao, Ruxue Fan, and Yong Wang*, In-Situ Formed Bimetallic Carbide Ni6Mo6C Nanodots and NiMoOx Nanosheet Arrays Hybrids Anchored on Carbon Cloth: Efficient and Flexible Self-supported Catalysts for Hydrogen Evolution, ACS Catal., 2020, 10, 19, 11634-11642.
4. Zhe Wang1, Yuzhuo Chen1, Shanjun Mao1, Kejun Wu2, Kaichao Zhang2, Qichuan Li2 and Yong Wang1*, Chemical insight into the structure and formation of coke on PtSn alloy during propane dehydrogenation, Adv. Sustain. Syst., 2020, 2000092.
5. Xiaobing Bao1, Yutong Gong1, Xiaozhong Zheng, Jiayi Chen, Shanjun Mao, Yong Wang*, Highly performed platinum nanosheets synthesized under in situ reaction conditions for hydrogen generation, J. Ener. Chem., 2020, 51, 272-279.
6. Chunpeng Wang, Shanjun Mao*, Zhe Wang, Yuzhuo Chen, Wentao Yuan, Yang Ou, Hao Zhang, Yutong Gong, Yong Wang, Bingbao Mei, Zheng Jiang, and Yong Wang*,Insight into Single-atom Induced Unconventional Size-dependence over CeO2-supported Pt Catalysts, Chem., 2020, 6, 752-765.
7. Jinrong Liu,‡ Lei Xie,‡ Zhe Wang, Shanjun Mao, Yutong Gong, and Yong Wang*, Biomass-derived ordered mesoporous carbon nano-ellipsoids encapsulated metal nanoparticles inside: ideal nanoreactors for shape-selective catalysis. Chem. Commun., 2020, 56, 229-232.
2019年
1. Haiyan Wang, Yuzhuo Chen, Ruxue Fan, Jiadong Chen, Zhe Wang, Shanjun Mao, Yong Wang*, Selective Electrochemical Reduction of Nitrogen to Ammonia by Adjusting the Three-Phase Interface, Research, 2019, 2019, 1401209.
2. Zhenzhen Wang, Chunpeng Wang, Shanjun Mao, Yutong Gong, Yuzhuo Chen and Yong Wang*, Pd nanoparticles anchored on amino-functionalized hierarchically porous carbon for efficient dehydrogenation of formic acid at ambient condition, J. Mater. Chem. A, 2019,7, 25791-25795.
3. Lei Xie, Zhe Wang, Jinrong Liu, Yutong Gong, Shanjun Mao, Guofeng Lü, Xiao Ma, Lili Yu, Yong Wang, Kinetics-controlled synthesis of hierarchically porous materials with tunable properties from diverse building blocks, Carbon, 2019,155, 611-617.
4. Shanjun Mao, Bowen Zhao, Zhe Wang, Yutong Gong, Guofeng Lü, Xiao Ma, Lili Yu, Yong Wang, Tuning the Catalytic Performance for the Semi-hydrogenation of Alkynols by Selectively Poisoning the Active Sites of Pd Catalysts, Green Chem., 2019, 21, 4143-4151.
5. Jinrong Liu, Lei Xie, Jiang Deng, Yutong Gong, Guping Tang, Hongzhen Bai*, Yong Wang*, Annular mesoporous carbonaceous nanospheres from biomass-derived building units with enhanced biological interactions, Chem. Mater., 2019, 31, 7186-7191.
6. Shanjun Mao; Chunpeng Wang; Yong Wang*, The chemical nature of N doping on N doped carbon supported noble metal catalysts. J. Catal., 2019, 375, 456-465.
7. Wang, Haiyan; Fan, Ruxue; Miao, Jingyu; Deng, Jiang; Wang, Yong*, Oxygen Groups Immobilized in Micropores for Enhancing the Pseudocapacitance, ACS Sus. Chem. & Eng., 2019, 7, 11407-11414.
8. Yong Wang, Preface to special issue on celebrating the 40th anniversary of Institute of Catalysis, Zhejiang University, Chin. J. Catal., 2019, 40, 969-970 (Preface).
9. Xiaobing Bao,a Yutong Gong,*a Yuzhuo Chen,a Hao Zhang,b Zhe Wang,a Shanjun Mao,a Lei Xie,a Zheng Jiang*b and Yong Wang*a, Carbon vacancy defect-activated Pt cluster for hydrogen generation, J. Mater. Chem. A 2019, 7, 15364-15370.
10. Jiayi Chen, Haiyan Wang, Zhe Wang, Shanjun Mao, Jian Yu, Yong Wang, Yong Wang *, Re-dispersion of Mo-based Catalysts and the Rational Design of Super Small-sized Metallic Mo Species, ACS Catal., 2019, 9, 5302-5307.
11. Yuzhuo Chen, Xiangqian Kong, Shanjun Mao, Zhe Wang,Yutong Gong, Yong Wang*, Study on the Role of Alkaline Sodium Additive in Selective Hydrogenation of Phenol, Chin. J. Catal., 2019, 40, 1516-1524.
12. Jiadong Chen, Haiyan Wang*, Yutong Gong and Yong Wang*, Directly Immobilizing Ru-Tannic Acid linkage coordination Complex on Carbon Cloth: An Efficient and Ultrastable Catalyst for Hydrogen Evolution Reaction, J. Mater. Chem. A, 2019,7, 11038-11043 (2019 Journal of Materials Chemistry A HOT Papers)
13. Yuzhuo Chen, Zhe Wang, Shanjun Mao, Yong Wang*,Rational design of hydrogenation catalysts by using nitrogen doped porous carbon,Chin. J. Catal., 2019, 40, 971-979.
14. Chunhong Chen, Lei Xie, and Yong Wang*, Recent advances in the synthesis and applications of anisotropic carbon and silica-based nanoparticles, Nano Research, 2019, 12, 1267-1278 (Invited Review).
2018年
1. Xuefeng Li‡, Zhe Wang‡, Shanjun Mao*, Yiqing Chen, Minghui Tang, Haoran Li, Yong Wang*, Insight into the Role of Additives in Catalytic Synthesis of Cyclohexylamine from Nitrobenzene, Chin. J. Chem. 2018, 36, 1191-1196.
2. Haiyan Wang, Jiayi Chen, Ruxue Fan, Yong Wang*, A Flexible Dual Solid-State Electrolyte Supercapacitor with Suppressed Self-Discharge and Enhanced Stability, Sustainable Energy & Fuels, 2018, 2, 2727-2732.
3. Lei Xie, Xuefeng Li, Jiang Deng, Yutong Gong, Haiyan Wang, Shanjun Mao, Yong Wang*, Sustainable and scalable synthesis of monodisperse carbon nanospheres and their derived superstructures, Green Chem. 2018, 20, 4596-4601.
4. Xiangqian Kong; Zhongfeng Fang; Xiaobing Bao; Zhe Wang; Shanjun Mao*; Yong Wang*, Efficient Hydrogenation of Stearic Acid over Carbon Coated Ni-Fe Catalyst, J. Catal. 2018, 367, 139-149.
5. Lei Xie, Haiyan Wang, Chunhong Chen, Shanjun Mao, Yiqing Chen, Haoran Li, Yong Wang*, Cooperative assembly of asymmetric carbonaceous bivalve-like superstructures from multiple building blocks, Research, 2018, 2018, 5807980.
6. Yueling, Cao; Bowen, Zhao; Xiaobing, Bao; Yong, Wang*. Fabricating metal@N-doped carbon catalysts via a thermal method. ACS Catal. 2018, 8, 7077-7085.
7. Chunhong Chen+, Xuefeng Li+, Jiang Deng, Zhe Wang, Yong Wang*, Shape Engineering of Biomass-Derived Nanoparticles from Hollow Spheres to Bowls via Solvent-Induced Buckling, ChemSusChem, 2018, 11, 2540-2546. (VIP Paper).
8. Haiyan, Jin; Jiayi, Chen; Shanjun, Mao; Yong, Wang*,Transition-metal induced the contraction of tungsten carbide lattice as superior hydrogen evolution reaction catalyst, 2018, ACS Appl. Mater. & Inter., 10, 22094–22101.
9. Haiyan Jin, Hao Zhang, Jiayi Chen, Shanjun Mao, Zheng Jiang* and Yong Wang*, A General Synthetic Approach for Hexagonal Phase Tungsten Nitride Composites and Their Application in Hydrogen Evolution Reaction, J. Mater. Chem. A. 2018, 6, 10967-10975.
10. Jiayi Chen, Haiyan Wang*, Jiang Deng, Chunmei Xu,Yong Wang*,Low-crystalline Tungsten Trioxide Anode with Superior Electrochemical Performance for Flexible Solid-state Asymmetry Supercapacitor. J. Mater. Chem. A. 2018, 6, 8986-8991.
11. Haiyan Wang, Ruxue Fan, Jingyu Miao, Jiayi Chen, Shanjun Mao, Jiang Deng and Yong Wang*, Oxygen vacancies on the surface of HxWO3-y for enhanced charge storage. J. Mater. Chem. A. 2018, 6, 6780-6784.
12. Xiangqian Kong, Yutong Gong,* Shanjun Mao, and Yong Wang*, Selective Hydrogenation of Phenol, ChemNanoMat, 2018, 4, 432-450.
13. Jing Wang, Zhongzhe Wei, ShanJun Mao, Haoran Li, Yong Wang*, Highly uniform Ru nanoparticles over N-doped carbon: pH and temperature-universal hydrogen release from water reduction, Energ. Environ. Sci., 2018, 11, 800-806.
14. Yiqing Chen, Xuefeng Li, Zhongzhe Wei, Shanjun Mao, Jiang Deng, Yueling Cao, Yong Wang*, Efficient synthesis of ultrafine Pd nanoparticles on an activated N-doping carbon for the decomposition of formic acid. Catal. Commun. 2018, 108, 55-58.
15. Zhongzhe Wei, Xuefeng Li, Jiang Deng, Jing Wang, Haoran Li, Yong Wang*,Improved catalytic activity and stability for hydrogenation of levulinic acid by Ru/N-doped hierarchically porous carbon. Molecular Catal. 2018, 448, 100-107.
16. Zhongzhe Wei, Yi Li, Jing Wang, Haoran Li, Yong Wang*, Chemoselective hydrogenation of phenol to cyclohexanol using heterogenized cobalt oxide catalysts, Chinese Chemical Letters, 2018, 29, 815-818.
17. Zhongzhe Wei, ShanJun Mao, Fanfei Sun, Jing Wang, Bingbao Mei, Yiqing Chen, Haoran Li and Yong Wang*,The synergic effects at molecular level in CoS2 for selective hydrogenation of nitroarenes, Green Chem. 2018, 20, 671-679.
18. 王哲, 毛善俊, 李浩然, 王勇*, 维生素E的催化合成路线分析(How to synthesize Vitamin E), 物理化学学报(Acta. Phys.-Chim. Sin), 2018, 34, 598-617.
19. Chunmei Xu, Haiyan Wang, Jiang Deng, Yong Wang*, High-performance Flexible Redox Supercapacitors Induced by Methylene Blue with a Wide Voltage Window.Sustainable Energy & Fuels, 2018, 2, 357-360.
20. Mingming Li, L. Yi, Lu Jia, Yong Wang*,Tuning the selectivity of phenol hydrogenation on Pd/C with acid and basic media, Catal. Commun. 2018, 103, 88-91.
2017年
1. Yueling Cao, Shanjun Mao, Mingming Li, Yiqing Chen, and Yong Wang*, Metal/porous carbon composites for heterogeneous catalysis: old catalysts with improved performance promoted by N-doping. ACS Catal. 2017,7,8090-8112.
2. Jiang Deng†, Michael R. Nellist‡, Michaela Burke Stevens‡, Christian Dette‡, Yong Wang†, and Shannon W. Boettcher*‡,Morphology Dynamics of Single-Layered Ni(OH)2/NiOOH Nanosheets and Subsequent Fe Incorporation Studied by in Situ Electrochemical Atomic Force Microscopy,Nano Lett., 2017,17,6922-6926.
3. Cao Yueling, Tang Minghui, Li Mingming, Deng Jiang, Xu, Fan, Xie Lei, Wang Yong*, In situ synthesis of chitin-derived Rh/N-C catalysts: efficient hydrogenation of benzoic acid and derivatives, ACS Sustainable Chem. Eng. 2017, 5, 9894-9902.
4. Mingming Li, Jiang Deng, Yikai Lan, Yong Wang*, Efficient Catalytic Hydrodeoxygenation of Aromatic Carbonyls over a Nitrogen-Doped Hierarchical Porous Carbon Supported Nickel Catalyst, ChemistrySelect. 2017, 2, 8486-8492.
5. Haiyan Wang, Chunmei Xu, Yiqing Chen and Yong Wang*,MnO2 nanograsses on porous carbon cloth for flexible solid-state asymmetric supercapacitors with high energy density, Energy Storage Mater. 2017, 8, 127-133.
6. Jing Wang, Zhongzhe Wei, Haiyan Wang, Yiqing Chen, Yong Wang*, CoOx-carbon nanotubes hybrids integrated on carbon cloth as a new generation of 3D porous hydrogen evolution promoter,J. Mater. Chem. A, 2017, 5, 10510-10516.
7. Xiaobing Bao, Jing Wang, Xu Lian, Haiyan Jin, Shiping Wang and Yong Wang*,Ni/Nitrogen-doped graphene nanotubes acted as a valuable tailor for remarkably enhanced hydrogen evolution performance of Platinum-based catalysts. J. Mater. Chem. A, 2017, 5, 16249-16254.
8. Minghui Tang‡, Shanjun Mao‡, Xuefeng Li, Chunhong Chen, Mingming Li and Yong Wang*, Highly effective Ir-based catalysts for the benzoic acid hydrogenation: experiment and theory guided catalysts rational design. Green Chem. 2017, 19, 1766-1774.
9. Haiyan Wang, Jiang Deng, Chunmei Xu, Yiqing Chen, Fan Xu and Yong Wang*, Ultramicroporous Carbon Cloth for Flexible Energy Storage with High Areal Capacitance, Energy storage Mater. 2017, 7, 216-221.
10. Jing Wang,Shanjun Mao, Zeyan Liu, Zhongzhe Wei, Haiyan Wang, Yong Wang*, The Dominating Role of Ni0 on the Interface of Ni/NiO for Enhanced Hydrogen Evolution Reaction. ACS Appl. Mater. Interfaces, 2017, 9, 7139-7147.
11. Chunhong Chen, Haiyan Wang, Chuanlong Han, Jiang Deng, Jing Wang, Mingming Li, Minghui Tang, Haiyan Jin, and Yong Wang*, Asymmetric flask-like hollow carbonaceous nanoparticles fabricated by the synergistic interaction between soft template and biomass. J. Am. Chem. Soc. 2017, 139, 2657-2663.
12. Lingfeng Shen, Shanjun Mao, Jianqing Li, Mingming Li, Ping Chen, Haoran Li, Zhirong Chen and Yong Wang*, PdZn intermetallic on a CN@ZnO hybrid as an efficient catalyst for the semi-hydrogenation of alkynols, J. Catal. 2017, 350, 13-20.
13. Jing Wang, Fan Xu, Haiyan Jin, Yiqing Chen and Yong Wang*, Non-noble Metal-based Carbon Composites in Hydrogen Evolution Reaction: Fundamentals to Applications, Adv. Mater. 2017, 29, 1605838.
14. Haiyan Jin, ShanJun Mao, Guopeng Zhan, Fan Xu, Xiaobing Bao and Yong Wang*. Fe incorporated α-Co(OH)2 nanosheet with remarkably improved activity and stability towards oxygen evolution reaction. J. Mater. Chem. A, 2017,5, 1078-1084.
15. Xiaobing Bao,‡ Yutong Gong,‡ Jiang Deng, Shiping Wang, Yong Wang* Organic acid-assisting Synthesis of 3D Lasagna-like Fe-N-doped CNTs-G Framework: An Efficient and Stable Electrocatalyst for Oxygen Reduction Reaction. Nano Research 2017, 10, 1258-1267.
2016年
1. Minghui Tang, Jiang Deng, Mingming Li, Xuefeng Li, Haoran Li ,Zhirong Chen and Yong Wang*. 3D-interconnected Hierarchical Porous N-doped Carbon Supported Ruthenium Nanoparticles as an efficient catalyst for Hydrogenation of Toluene and Quinoline. Green Chem.2016, 18, 6082-6090.
2. Zhongzhe Wei, Yiqing Chen, Jing Wang, Diefeng Su, Minghui Tang, Shanjun Mao, Yong Wang*. Cobalt encapsulated in N-doped graphene layers: an efficient and stable catalyst for hydrogenation of quinoline compounds. ACS. Catal., 2016,5816–5822
3. Fan Xu, Yiqing Chen, Minghui Tang, Haiyan Wang, Jiang Deng, and Yong Wang*, Acid Induced Self-Assembly Strategy to Synthesize Ordered Mesoporous Carbons from Biomass. ACS Sustainable Chem. Eng., 2016, 4,4473–4479.
4. Mingming Li, Minghui Tang, Jiang Deng, and Yong Wang*. Nitrogen-doped flower-like porous carbon directed by in situ hydrolysed MgO: Promising support for Ru nanoparticles in catalytic hydrogenations. Nano Res. 2016, 9,3129–3140.
5. Jiang Deng, Mingming Li, Yong Wang*, Biomass-derived Carbon: Synthesis and Application on Energy Storage and Conversion, Green Chem., 2016,18, 4824-4854
6. Jiang Deng, Tianyi Xiong, Haiyan Wang, Anmin Zheng, and Yong Wang*, Effects of Cellulose, Hemicellulose, and Lignin on the Structure and Morphology of Porous Carbons. ACS Sustainable Chem. Eng.,2016, 4, 3750–3756.
7. Wang, H. Y.; Deng, J.; Chen, Y .Q.; Xu, F.; Wei, Z. Z, and Wang, Y.* Hydrothermal synthesis of manganese oxide encapsulated multiporous carbon nanofibers for supercapacitors. Nano Research, 2016, 9, 2672-2680.
8. Li, M. M.; Xu, F.; Li, H. R. and Wang, Y.* Nitrogen-doped porous carbon materials: promising catalysts or catalyst supports for heterogeneous hydrogenation and oxidation. Catal. Sci. Technol. 2016, 6, 3670-3693.(2016 most accessed Catalysis Science and Technology articles)
9. Su, D. F.; Wei, Z. Z.; Mao, S. J.; Wang, J.; Li, Y.; Li, H. R.; Chen, Z. R.; Wang, Y.* Reactivity and mechanism investigation of selective hydrogenation of 2,3,5-trimethylbenzoquinone on in situ generated metallic cobalt. Catal. Sci. Technol., 2016, 6,4503–4510.
2015年
1. Wang, S. P.#; Wang, J.#; Zhu, M. L.; Bao, X. B.; Xiao, B. Y.; Su, D. F.; Li, H. R.; Wang, Y.* Molybdenum carbide-modified nitrogen-doped carbon vesicle encap-sulating nickel nanoparticles: A highly efficient, low-cost catalyst for hydrogen evolution reaction. J. Am. Chem. Soc. 2015, 137, 15753-15759.
2. Wei, Z. Z.#; Wang, J.#; Mao, S. J; Su, D. F; Jin, H. Y.; Wang, Y. H.; Xu, F.; Li, H. R.; Wang, Y.* In Situ Generated Co0-Co3O4/N-Doped Carbon Nanotubes Hybrids as Efficient and Chemoselective Catalysts for Hydrogenation of Nitroarenes. ACS. Catal. 2015, 5, 4783-4789.
3. Wang, J.; Wei, Z. Z.; Gong, Y. T.; Wang, S. P.; Su, D. F.; Han, C. L.; Li, H. R.; Wang, Y.* Ni-promoted Synthesis of Graphitic Carbon Nanotubes from in situ Produced Graphitic Carbon for Dehydrogenation of Ethylbenzene. Chem. Commun. 2015, 51, 12859-12862.
4. Deng, J.; Xiong, T. Y.; Xu, F.; Li, M. M.; Han, C. L.; Gong, Y. T.; Wang, H. Y.; Wang, Y.* Inspired by Bread Leavening: One-pot Synthesis of Hierarchically Porous Carbon for Supercapacitors. Green Chem. 2015, 7, 4053-4060.
5. Su, D. F.; Wang, J.; Jin, H. Y.; Gong, Y. T.; Li, M. M.; Pang, Z. F.; Wang Y.* From “Waste to Gold&rdqurdquo;: One-pot Way to Synthesize Ultrafinely Dispersed Fe2O3-based Nanoparticles on N-doped Carbon for Synergistically and Efficiently Water Splitting. J. Mater. Chem. A. 2015, 3, 11756-11761.
6. Wang, S. P.; Zhu, M. L.; Bao, X. B.; Wang, J.; Chen, C. H.; Li, H. R.; Wang, Y.* Efficient Synthesis of Mesoporous Fe-N/C Materials with High Catalytic Performance for Oxygen Reduction Reaction. ChemCatChem. 2015, 7, 2937-2944. (Invited)
7. Zhang, P. F.; Deng, J.; Mao, J. Y.; Li, H. R.; Wang, Y.* Selective aerobic oxidation of alcohols by a mesoporous graphitic carbon nitride/N-hydroxyphthalimide system under visible-light illumination at room temperature. Chin. J. Catal. 2015, 36, 1580-1586. (Invited)
8. Tang, M. H.; Mao, S. J.; Li, M. M.; Wei, Z. Z.; Xu, F.; Li, H. R.; Wang, Y.* RuPd Alloy Nanoparticles Supported on N-Doped Carbon as an Efficient and Stable Catalyst for Benzoic Acid Hydrogenation. ACS Catal. 2015, 5, 3100-3107.
9. Jin, H. Y.; Wang, J.; Su, D. F.; Wei, Z. Z.; Pang, Z. F.; Wang, Y.* In-situ cobalt-cobalt oxide/N-doped carbon hybrids as superior bi-functional electrocatalysts for hydrogen and oxygen evolution. J. Am. Chem. Soc. 2015, 137, 2688-2694.
10. Gong, Y. T.; Li, M. M.; Wang, Y.* Carbon Nitride in Energy Conversion and Storage: Recent Advances and Future Prospects. ChemSusChem. 2015, 8, 931-946. (Invited Review).
11. Gong, Y. T.; Li, M. M.; Li, H. R.; Wang, Y.* Graphitic carbon nitride polymers: Promising catalysts or catalyst supports for heterogeneous oxidation and hydrogenation. Green Chem. 2015, 17, 715-736. (2015 most accessed Green Chemistry articles).
12. Wei, Z. Z.; Gong, Y. T.; Xiong, T. Y.; Zhang, P. F.; Li, H. R.; Wang, Y.* Highly efficient and chemoselective hydrogenation of α, βbeta;-unsaturated carbonyls over Pd/N-doped hierarchically porous carbon. Catal. Sci. Technol. 2015, 5, 397-404 .
2014年
1. Han, C. L.; Wang, S. P.; Wang, J.; Li, M. M.; Deng, J.; Li, H. R.; Wang, Y.* Controlled Synthesis of Sustainable N-doped Hollow Core Mesoporous Shell Carbonaceous Nanospheres from Biomass. Nano. Res. 2014,7, 1809-1819.
2. Wang, S. P.; Han, C. L.; Wang, J.; Deng, J.; Zhu, M. L.; Yao, J.; Li, H. R.; Wang, Y.* Controlled Synthesis of Ordered Mesoporous Carbohydrate-derived Carbons with Flower-like Structure and N-doping by Self-transformatio. Chem. Mater. 2014, 26, 6872-6877.
3. Gong, Y. T.; Wang, H. Y.; Wei, Z. Z.; Xie, L.; Wang, Y.* An efficient way to introduce hierarchical structure into biomass-based hydrothermal carbonaceous materials. ACS Sustain. Chem. Eng. 2014, 2, 2435-2441.
4. Wang, S. P; Liu, R. H.; Han, C. L; Wang, J.; Li, M. M.; Yao, J.*; Li, H. R.; Wang, Y.* A novel strategy to synthesize hierarchical porous carbohydrate-derived carbon with tunable properties. Nanoscale, 2014, 6, 13510-13517.
5. Wang, H. Y; Gong, Y. T.; Wang, Y.* Cellulose-based hydrophobic carbon aerogels as versatile, and superior adsobents for sewage treatment. RSC Adv. 2014, 4, 45753-45759.
6. Gong, Y. T.; Xie, L.; Li, H. R.; Wang, Y.* Sustainable and scalable production of monodisperse and highly uniform colloidal carbonaceous spheres using sodium polyacrylate as dispersant. Chem. Commun. 2014, 50, 12633-12636.
7. Jin, H. Y.; Xiong, T. Y.; Li, Y.; Xu, X.; Li, M. M.; Wang, Y.* Improvedelectrocatalytic activity for ethanol oxidation by Pd@N-doped carbon from biomass. Chem. Commun. 2014, 50, 12637-12640.
8. Gong, Y. T.; Wei, Z. Z.; Wang, J.; Zhang, P. F.; Li, H. R.; Wang, Y.* Design and Fabrication of Hierachically Porous Carbon with a Template-free Method. Sci. Rep. 2014, 4, 6349.
9. Xu, X.; Li, H. R.; Wang, Y.*Selective Hydrogenation of Phenol to Cyclohexanone in Water over Pd@N-doped Carbon Derived from Ionic Liquids Precursors. ChemCatChem. 2014, 6, 3328-3332.
10. Xu, X.; Tang, M. H.; Li, M. M.; Li, H. R.; Wang, Y.* Hydrogenation of Benzoic Acid and Derivatives over Pd Nanoparticles Supported on N-doped Carbon Derived from Glucosamine Hydrochloride. ACS Catal. 2014, 4, 3132-3135.
11. Zhang, P. F.; Gong, Y. T.; Wei, Z. Z.; Wang, J.; Zhang, Z. Y.; Li, H. R.; Dai, S.; and Wang, Y.* Updating Biomass into Functional Carbon Material in Ionothermal Manner. ACS Appl. Mater. Interfaces. 2014, 6, 12515-12522
12. Li, M. M.; Xu, X.; Gong, Y. T.; Wei, Z. Z.; Hou, Z. Y.; Li, H. R.; Wang, Y.* Ultrafinely Dispersed Pd Nanoparticles on a CN@MgO Hybrid as a Bifunctional Catalyst for Bioderived Compounds Upgrading. Green Chem. 2014, 16, 4371-4377.
13. Zhang, P. F.; Li, H. R.; Wang, Y.* Post-Functionalization of Graphitic Carbon Nitride by Grafting Organic Molecule: Toward C-H Bond Oxidation Using Atmospheric Oxygen. Chem. Commun. 2014, 50, 6312-6315.
14. Gong, Y. T.; Wang, J.; Wei, Z. Z.; Zhang, P. F.; Li, H. R.; Wang, Y.* Combination of carbon nitride and carbon nanotubes: catalysts in energy conversion. ChemSusChem. 2014, 7, 2303-2309.
15. Wang, J.; Xu, Z.; Gong, Y. T.; Han, C. L.; Li, H. R.; Wang, Y.* One-Step Production of Sulfur and Nitrogen Co-doped Graphitic Carbon for Oxygen Reduction: Activation Effect of Oxidized Sulfur and Nitrogen. ChemCatChem. 2014, 6, 1204-1209.
16. Chen, K. X.; Zhang, P. F.; Wang, Y.; Li, H. R.* Metal-free allylic/benzylic oxidation strategies with molecular oxygen: recent advances and future prospect. Green Chem. 2014, 16, 2344-2374. Invited Review
17. Song, T.; Zhou, B.; Peng, G. W.; Zhang, Q. B.; Wu, L. Z.; Liu, Q.*, Wang, Y.*. Aerobic Oxidative Coupling of Resveratrol and its Analogues by Visible Light Using Mesoporous Graphitic Carbon Nitride (mpg-C3N4) as a Bioinspired Catalyst. Chem. A Eur. J. 2014, 20, 678-682.
18. Han, C. L.; Wang, J.; Gong, Y. T.; Xu, X.; Li, H. R.; Wang, Y.* Nitrogen-Doped Hollow Carbon Hemispheres as Efficient Metal-Free Electrocatalysts for Oxygen Reduction Reaction in Alkaline Medium. J. Mater. Chem. A, 2014, 2, 605-609.
2013年
1. Soll, S.; Zhang, P. F.; Zhao, Q.; Wang, Y.; Yuan, J. Y.* Mesoporous Zwitterionic Poly(ionic liquid): Intrinsic Complexation and Efficient Catalytic Fixation of CO2. Polymer, 2013, 4, 5048-5051.
2. Deng, D. X.;* Yang, Y.; Gong, Y. T.; Li, Y.; Xu, X.; Wang, Y.* Palladium nanoparticles supported on mpg-C3N4 as active catalyst for semihydrogenation of phenylacetylene under mild conditions.Green Chem.2013, 15, 2525-2531.
3. Yao, Y.; Xue, M.; Zhang, Z. B.; Zhang, M. M.; Wang, Y.; Huang, F. H.* Gold nanoparticles stabilized by an amphiphilic pillar
4. Li, Y.; Xu, X.; Zhang, P. F.; Gong, Y. T.; Li, H. R.; Wang, Y.*Highly Selective Pd@mpg-C3N4 Catalyst for Phenol Hydrogenation in Aqueous Phase. RSC Adv. 2013, 3, 10973-10982.
5. Zhang, P. F.; Yuan, J. Y.*; Tim-Patrick,F.; Antonietti, M.; Li, H. R.; Wang, Y.* Improving Hydrothermal Carbonization by Poly(ionic liquid)s. Angew. Chem. Int. Ed. 2013, 52, 6028-6032.
6. Zhang, P. F.; Gong, Y. T.; Li, H. R.; Chen, Z. R.; Wang, Y.* Selective oxidation of benzene to phenol by FeCl3/mpg-C3N4 hybrids. RSC Adv. 2013, 3, 5121-5126.
7. Zhang, P. F.; Gong, Y. T.; Li, H. R.; Chen, Z. R.; Wang, Y.* Solvent-free aerobic oxidation of hydrocarbons and alcohols with Pd@N-doped carbon from glucose. Nat. Commun. 2013, 4, 1593.
8. Zhang, P. F.; Yuan, J. Y.; Li, H. R.; Liu, X. F.; Xu, X.; Antonietti, M.; Wang, Y.* Mesoporous Nitrogen-Doped Carbon for Copper-Mediated Ullmann-type C-O/-N/-S Cross-Coupling Reactions. RSC. Adv., 2013, 3, 1890-1895.
9. Gong, Y. T.; Zhang, P. F.; Xu, X.; Li, Y.; Li, H. R.;Wang, Y.* A Novel Catalyst Pd@ompg-C3N4 for Highly Chemoselective Hydrogenation of Quinoline under Mild Conditions, J. Catal. 2013, 297, 272-280.
2012年
1. Xu, X.; Li, Y.; Gong, Y. T.; Zhang, P. F.; Li, H. R.; Wang, Y.* Synthesis of Palladium Nanoparticles Supported on Mesoporous N-Doped Carbon and Their Catalytic Ability for Biofuel Upgrade. J. Am. Chem. Soc. 2012, 134, 16987-16990.
2. Li, Y.; Gong, Y. T.; Xu, X.; Zhang, P. F.; Li, H. R.; Wang, Y.* A practical and benign synthesis of amines through Pd@mpg-C3N4 catalyzed reduction of nitriles. Catal. Commun. 2012, 28, 9-12.
3. Zhang, P. F.; Wang, Y.*; Li, H. R.*; Antonietti, M. Metal-free oxidation of sulfides by carbon nitride with visible light illumination under room temperature. Green Chem. 2012, 7, 1904-1908.
4. Zhang, P. F.; Gong, Y. T.; Lv, Y. Q.; Guo, Y.; Wang, Y.; Wang, C. M.; Li, H. R.* Ionic liquids with metal chelate anions. Chem. Commun. 2012, 48, 2334-2336.
5. Wang, Y.; Wang, X.; Antonietti, M.* Polymeric graphitic carbon nitride as a heterogenous organocatalyst: from photochemistry to multipurpose catalysis in sustainable chemistry. Angew. Chem. Int. Ed. 2012, 51, 68-89. invited review.
2011年
1. Zhu, X.; Wang, Y.; Li, H.* Do all the protic ionic liquids exist as molecular aggregates in the gas phase? Phys. Chem. Chem. Phys., 2011, 13, 17445-17448.
2. Zhang, P.; Wang, Y.; Yao, J.; Wang, C.; Antonietti, M.; Li, H.* Visible-light-induced metal-free allylic oxidation utilizing a coupled photocatalytic system of g-C3N4 and N-hydroxy compounds. Adv. Synth. & Catal. 2011, 353, 1447-1451.
3. Wang, Y.;* Yao, J.; Li, H.;* Su, D.; and Antonietti, M. Highly selective hydrogenation of phenol and derivatives over a Pd@carbon nitride catalyst in aqueous media. J. Am. Chem. Soc. 2011,133, 2362-2365.
4. Wang, Y.;* Li, H.; Yao, J.; Wang, X.; and Antonietti, M. Synthesis of boron doped polymeric carbon nitride and their use as metal-free catalysts for aliphatic C-H bond oxidation. Chem. Sci. 2011, 2, 446-450. (Highlighted by Chem. & Eng. News, 2010-12-13, amongst the top ten accessed articles).
2010年
1. Wang, Y.;* Zhang, J.; Wang, X.; Antonietti, M.; and Li, H.* Boron- and fluorine-containing mesoporous carbon nitride polymers: metal-free catalysts for cyclohexane oxidation. Angew. Chem. Int. Ed. 2010, 49, 3356-3359.
2. Wang, Y.; Wang, X.; Antonietti, M.; and Zhang, Y.* Facile one-pot synthesis of nanoporous carbon nitride solids by using soft templates. ChemSusChem, 2010, 3, 435-439.
3. Wang, Y.;* Di, Y.; Antonietti, M.; Li, H.; Chen, X.; and Wang, X. Excellent visible-light photocatalysis of fluorinated polymeric carbon nitride solids. Chem. Mater. 2010, 22, 5119-5121.
4. Gao, Y.; Zhang, L. Q.; Wang, Y.; and Li, H.* Probing electron density of H-bonding between cation-anion of imidazolium-based ionic liquids with different anions by vibrational spectroscopy. J. Phys. Chem. B 2010, 113, 2828-2833.
2009年
1. Wang, Y.; Xu, Z.; Gao, Y.; and Li, H.* Probing the strength changes in C-H and C-C bonds for cation/pi complexes. J. Phys. Chem. A 2009, 113, 7097-7102.
2. Zhu, X.; Wang, Y.; and Li, H.* The structural organization in aqueous solutions of ionic iquids. AIChE J. 2009, 55, 198-205.
3. Zhang, L.; Wang, Y.; Xu, Z.; and Li, H.* Comparison of the blue-shifted C-D stretching vibrations for D">J. Phys. Chem. B 2009, 113, 5978-5984.
4. Wang, C.; Guan, W.; Xie, P.; Yun, X.; Li, H.;* Hu, X.; Wang, Y. Effects of ionic liquids on the oxidation of 2,3,6-trimethylphenol to trimethyl-1,4-benzoquinone under atmospheric oxygen. Catal. Commun. 2009, 5, 725-727.
2008年
1. Wang, Y.; Wang, C.; Zhang, L.; and Li, H.* Difference for SO2 and CO2 in TGML ionic liquids: a theoretical investigation. Phys. Chem. Chem. Phys. 2008, 10, 5976-5982.
2. Zhang, L.; Xu, Z.; Wang, Y.; and Li, H.* Prediction of the solvation and structural properties of ionic liquids in water by two-dimensional correlation spectroscopy. J. Phys. Chem. B 2008, 112, 6411-6419.
3. Guan, W.; Wang, C.; Yun, X.; Hu, X.; Wang, Y.; and Li, H.* A mild and efficient oxidation of 2,3,6-trimethylphenol to trimethyl-1,4-benzoquinone in ionic liquids. Catal. Commun. 2008, 9, 1979-1981.
2007年
1. Wang, Y.; Pan, H.; Li, H.;* and Wang, C. The force field of the TMGL ionic liquid and the solubility of SO2 and CO2 in the TMGL from molecular dynamics simulation. J. Phys. Chem. B 2007, 111, 10461-10467.
2. Zhang, L.; Li, H.;* Wang, Y.; and Hu, X. Characterizing the structural properties of N,N-dimethyl formamide-based ionic liquid: a density-functional study. J. Phys. Chem. B 2007, 111, 11016-11020.
3. Xu, X.; Wang, C.; Li, H.;* Wang, Y.; Sun, W.; and Shen, Z. Effects of imidazolium salts as cocatalysts on the copolymerization of CO2 with epoxides catalyzed by (Salen) Cr(ш)Cl complex. Polymer, 2007, 48, 3921-3924.
2006年
1. Wang, Y.; Li, H.;* and Han, S. A theoretical investigation of the interactions between water molecules and ionic liquids. J. Phys. Chem. B 2006, 110, 24646-24651.
2. Wang, Y.; Li, H.;* and Han, S. The chemical nature of the +C-H…X- (X= Cl or Br) interaction in imidazolium halide ionic liquids. J. Chem. Phys. 2006, 124, 044504.
3. Wang, C.; Guo, L.; Li, H.;* Wang, Y.; Weng, J.; and Wu, L. Preparation of simple ammounium ionic liquids and their application in the cracking of dialkoxypropanes. Green Chem. 2006, 8, 603-607.
4. Jiang, H.; Wang, C.; Li, H.;* and Wang, Y. Preparation of dialkoxypropanes in simple ammonium ionic liquids. Green Chem. 2006, 8, 1076-1079.
5. Weng, J.; Wang, C.; Li, H.;* and Wang, Y. Novel quaternary ammonium ionic liquids and their use as dual solvent-catalysts in the hydrolytic reaction. Green Chem. 2006, 8, 96-99.
6. 韩卫华,李浩然,* 邓东顺,王勇,硼氢化钠还原潜手性酮反应机理研究. 化学学报,2006, 64, 1723-1729.
2005年
1. Wang, Y.; Li, H.; Wu, T.; Wang, C.; and Han, S. Reaction mechanism study for the synthesis of alkylimidazolium-based halide ionic liquids. Acta Phys. –Chim. Sin. 2005, 21, 517-522.
2. Wang, Y.; Li, H.;* and Han, S. Structure and conformation properties of 1-alkyl- 3-methylimidazolium halide ionic liquids: A density functional theory study. J. Chem. Phys. 2005, 123, 174501.
2004年
1. 王勇,李浩然,*王从敏,许映杰,韩世钧,物理化学学报,单重态二溴卡宾与甲醛环加成反应的量化研究. 2004,20,1339-1344.
2. Xu, Y.; Li, H.;* Wang, C.; Wang, Y.; and Han, S. Bubble points measurement for (triethyl orthoformate + diethyl malonate). J. Chem. Thermodyn. 2004, 36, 971-976.
3. Wang, Y.; Li, H.;* Wang, C.; and Jiang, H. Ionic liquids as catalytic green solvents for cracking reactions. Chem. Commun. 2004, 1938-1839.
荣誉奖励:
1.王勇,王静,王世萍,金海燕,毛善俊,浙江省自然科学一等奖(2023)
2.王勇,毛善俊,王哲,浙江省专利一等奖(2023)
3.王勇,吕国锋,于丽丽,王哲,毛善俊,唐静思,李浩然,陈志荣,中国专利金奖(2023)
4.王勇,中国化学会催化委员会第九届中国催化青年奖(2023)
5.王勇,中国化工学会侯德榜化工科技-创新奖(2022)
6.2021年度新昌县十佳创新团队-浙江大学王勇团队
7.王勇,马啸,于丽丽,王哲,毛善俊,李建清,陈钢,李浩然,陈志荣,2021,中国石油与化学工业联合会专利金奖
8.王勇,毛善俊,于丽丽,吕国锋,王哲,2020年度浙江省科技奖-技术发明一等奖
9.王勇,陈志荣,吕国锋,毛善俊,王哲,李浩然,于丽丽,马啸,黄国东,胡柏剡等,2020,中国石油与化学工业联合会技术发明特等奖
10.2019年度新昌县科技创新优秀专家团队-浙江大学王勇团队
11.王勇,青年科技突出贡献奖,2018,中国石油和化学工业联合会
12.李浩然,马啸,胡柏剡,赵文乐,毛建拥,王勇,邱金倬,方万军,陈为超,仇丹,2018,中国轻工业联合会科学技术进步一等奖
13.王勇,国家高层次人才特殊支持计划青年拔尖人才,2015,中共中央组织部,人力资源和社会保障部
14.王勇,中国催化新秀奖,2014,中国化学会催化专业委员会
15.王勇,浙江省优秀博士后,2011,浙江省人力资源和社会保障厅
16.王勇,全国优秀博士学位论文提名论文,2010,教育部
王勇,浙江大学化学系特聘研究员,浙江大学–马普胶体与界面化学研究所“国际伙伴小组”组长。1979年出生于湖南汨罗,2002年本科毕业于湘潭大学,2007年博士毕业于浙江大学化工系,博士论文被评为浙江省优秀博士论文以及全国百篇优秀博士论文提名奖论文。2007年~2009年在浙江大学化学系从事博士后研究工作,合作导师李浩然教授,并荣获“浙江省优秀博士后”称号。2009年~2011年在德国马普胶体与界面化学研究所从事博士后研究工作,合作导师Markus Antonietti教授。2014年荣获“中国催化新秀奖”。2011年进入浙江大学工作至今,作为项目负责人承担多项国家自然科学基金、浙江省杰出青年基金及教育部博士点基金等。担任国际期刊Scientific Reports的编委。王勇研究组致力于新材料,尤其是新型多功能炭材料的开发以及多功能材料在传统多相催化反应,能源高效存储和转化等方面的应用。迄今已在Nat. Commun.,J. Am. Chem. Soc.; Angew. Chem. Int. Ed.; Chem. Mater.; J. Catal.等国际知名刊物上发表科研论文70余篇,H因子25。
一、功能炭材料的设计合成
炭材料因其优异的水热稳定性、良好的导电性、可修饰性和易于后处理等特性在作为催化剂载体和能源存储和转化材料(如超级电容器和燃料电池等)方面备受关注和研究。而传统的碳基材料如活性炭等在诸多方面无法适应实际应用中的要求(比表面积,孔道结构,表面化学性质等)。为了达到提高炭材料在催化或能源方面的利用效率,降低炭材料的生产成本等目的,需要设计合成具有特定功能或多功能的碳基材料。
1. 生物质基功能炭材料的开发
化石燃料的急剧消耗让以石油产品为碳源的炭材料合成方法前景堪忧。反之,以可再生的生物质为原料的炭材料合成方法表现出巨大的应用潜力。生物质水热法制备炭材料虽然具有原料来源广、生产成本低、可持续性好等特点,但孔道结构缺乏,水热产品形貌难控制等缺点一直限制其更广泛的应用。王勇研究组以水热法为基础,开发了微量添加剂辅助法可控合成了低尺寸炭微球以及尺寸均一的单分散炭微球,克服了生物质水热碳化法的产品形貌不均一,尺寸分布不一,尺寸难控制的缺点。另外研究组以水热法结合模板法技术,合成了中空、多孔生物质基功能炭材料,解决了软模板法难以合成有序多孔炭材料的难题。杂原子掺杂是调控碳基材料物理化学性质的有效方法。王勇团队利用水热合成法,原位焙烧法等合成了氮掺杂的多孔炭材料,通过在炭材料中引入电负性强的氮元素调变碳的电子结构,从而达到增强炭材料催化活性的目的。这些成果为炭材料的可控合成和应用提供了新方向。
2. 碳基复合材料的设计合成
单一炭材料活性低,无法满足实际应用中对材料活性及多功能化的需求。开发碳基复合材料是提高碳基材料活性的有效途径,但是如何将多孔炭材料与纳米金属或金属氧化物等进行有效地复合,提高碳基纳米复合材料的催化活性,是一大挑战。王勇研究团队针对催化和能源转化应用中的需求,开发了多种炭-炭复合材料,金属-炭和氧化物-炭复合材料。从纳米尺度,甚至是原子、分子尺度对碳基多相催化剂(电催化剂)的结构进行了有效的调控,极大地提高了其催化活性,拓展了其应用范围。如以生物质为碳源,通过与廉价金属Co复合制备得到CoOx@CN材料,该材料不仅是催化苯酚、硝基化合物等选择性加氢的优异催化剂,还能够高效地电催化水分解制备H2和O2。
二、碳基纳米催化剂在传统多相催化反应中的应用
1.在高效选择性加氢反应中的应用
优异的水热稳定性和高比表面积使得碳基材料成为非均相催化剂载体的理想选择。王勇研究员于2011年发现石墨型氮化碳作为载体负载纳米Pd(Pd@C3N4)催化苯酚加氢,在低温低压下即可获得高苯酚转化率(>99%)和高环己酮选择性(>99%),解决了苯酚选择性氢化高转化率和高选择性无法兼容的难点。实验研究和DFT计算研究表明,催化剂的高活性和高稳定性源于氮化碳中氮元素有利于提高Pd纳米颗粒的分散性并有效抑制Pd纳米颗粒的流失。催化剂的高选择性来源于氮化碳材料对底物苯酚的选择性吸附。不仅对于C=O的选择性加氢,Pd@C3N4对于C=N,C≡N和C≡C都具有优异的催化性能,如Pd@C3N4能催化喹啉高选择性氢化至1,2,3,4-四氢喹啉,苯乙炔到苯乙烯,腈基到叔胺等。
不仅具有高氮含量(氮含量=60 %)的氮化碳材料,以离子液体或氨基葡萄糖盐酸盐为原料制备的氮掺杂(氮含量≈10 %)多孔碳基材料作为Pd纳米催化剂的载体同样具有优异的催化性能。Pd@CN能高效地催化苯酚选择性加氢制备环己酮以及木质素模型分子-香兰素的加氢脱氧,同时还是催化苯甲酸选择性加氢的优异催化剂,且发现双金属Ru-Pd具有更加优异的催化活性。研究发现氮的含量及种类对催化活性有明显影响,这些研究结果为高效、高选择性加氢催化剂的设计提供了方向和理论依据。
2.在选择性氧化反应中的应用
针对环己烷选择性氧化制备环己酮等关键碳氢键氧化反应,王勇课题组开发了氮化碳与有机小分子NHPI的组合型催化剂,通过氮化碳与NHPI之间的电子转移极大地提高了催化剂的氧化活性。这种组合催化剂的思想还被成功地应用于醇类、硫化物等底物的选择性氧化反应中。以氮掺杂的多孔炭材料负载Pd纳米颗粒,以氧气或空气作为氧化剂,实现了C-OH和C-H键的高效、高选择性氧化反应。其中催化苯乙醇氧化至苯乙酮的TOF值可达到212,576 h-1,远高于其他载体负载的同类Pd催化剂。Pd-N之间的相互作用、小的Pd纳米尺寸和底物的有效吸附决定了该催化过程的高活性和高选择性。该类催化剂的开发有望解决传统催化中强氧化剂的使用和选择性差的问题。
三、碳基纳米催化剂在能源转化和存储方面的应用
1.能源储存 碳基纳米材料,尤其是多孔炭材料以其高比表面积、优异导电性成为双电层电容器的理想材料。炭材料的孔道结构是决定电容器性质的关键因素之一。王勇研究组以生物质为碳源,设计合成了多种多级大孔-介孔-微孔炭材料,材料不仅具有高达1000-2000 m2/g的比表面积,同时具有大孔-介孔比例高的特点,保证了材料不仅电解质吸附位点多且适于离子的传输,因而表现出优异的电荷储存和传输性能。
2.能源转化
作为可再生资源,醇类燃料(甲醇,乙醇)或氢能等成为替代化石能源最具前景的选择。燃料电池是高效转化醇类化学能到电能的装置,如何减少甚至消除昂贵的Pt基催化剂的使用是实现燃料电池大规模使用的关键。氮掺杂的碳基材料在燃料电池的阴极氧还原反应中表现出优于Pt基材料的高稳定性和低成本的优点。研究组开发的g-C3N4/CNTs复合材料和中空氮杂碳基微球在燃料电池阴极氧还原中性能优异。为进一步提高碳基材料的ORR活性,课题组在碳基材料中引入廉价金属如Fe等,制备得到Fe-N-C复合材料。该材料在碱性介质中表现出比Pt/C更优异的电催化活性与稳定性,在酸性条件下,Fe-N-C复合材料也具有优异的ORR活性。
在电解水制氢中,昂贵Pt/C催化剂的使用同样限制了其广泛应用,研究组开发的CoOx@CN材料催化剂具有接近Pt基催化剂的催化活性,该催化剂亦可作为析氧反应的催化剂,为非贵金属催化剂催化电解水提供了可能。
来源:科学成果管理与研究 2015年第8期
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