专家信息：
曹勇，1973年出生，江苏泗阳人，毕业于复旦大学化学系。现任复旦大学化学系教授，博士生导师。主要从事表面化学和多相催化研究，涉及纳米金属催化、固体酸碱催化、低碳烷烃的定向活化及选择氧化、生物质催化转化及其高附加值利用等领域。2014年获得第五届“中国催化青年奖”。
教育及工作经历：
1990年9月至1995年7月 复旦大学化学系，获理学学士学位。
1998年3月至2000年1月 新加坡国立大学理学院化学系，研究生联合培养。
1994年9月至2000年7月 复旦大学化学系，获理学博士学位。
2000年8月至2001年11月 复旦大学化学系工作，讲师。
2001年12月至2005年5月 复旦大学化学系工作，副教授/硕士生导师。
2005年6月至今 复旦大学化学系工作，教授/博士生导师。
学术兼职及社会任职：
1、2009年5月 至今 被聘为 Applied Catalysis A: General 编委。
2、2014年9月 至今 被聘为 《催化学报》编委。
3、参与J. Am. Chem. Soc.、J. Catal.和《高等学校化学学报》、《化学学报》、《物理化学学报》、《石油化工》等刊物的审稿。
主讲课程：
1、《现代化学专题-表面化学》
2、《物理化学（II）》
3、《催化反应机理》（研）
4、《高等结构分析》（工程硕士）
培养研究生情况：
指导研究生多名，其中3名已获硕士学位。
研究方向：
主要从事表面化学和多相催化研究，涉及高性能新结构纳米介孔催化材料的创制与绿色催化应用、低碳烷烃选择氧化制烯烃、1,3-丙二醇等聚酯原料关键单体的催化加氢合成、金属/半导体光催化、催化过程的原位动态谱学表征及C1资源的综合利用等。
承担科研项目情况：
主持在研或完成国家科技部863项目、国家自然科学基金重点项目、国家自然科学基金创新群体资助项目、上海市"青年科技启明星计划跟踪"等十余项科研项目。
1.核-壳式纳米复合催化剂的设计合成及其分子识别催化性。
2.新型金属/有机杂化催化剂的设计及直接法制H2O2研究。
3.甲醇氧化羰化制碳酸二甲酯新型纳米复合催化剂研究。
科研成果：
1 在新型纳米催化材料的研制及应用、催化原位谱学表征和催化理论的研究方面取得了一定的成果在Acc. Chem. Res.,Angew. Chem. Int. Ed., J. Am. Chem. Soc., Chem. Europ. J.,ChemSusChem,Chem. Commun., Green Chem., J. Catal., Adv. Synth. Catal., Langmuir等学术期刊发表SCI论文180余篇，他引3000余次。
2.申请中国发明专利32件(授权专利18件)。
2001年至今发表在Acc. Chem. Res.,Angew. Chem. Int. Ed., J. Am. Chem. Soc., Chem. Europ. J.,ChemSusChem,Chem. Commun., Green Chem., J. Catal., Adv. Synth. Catal., Langmuir等学术期刊发表SCI论文180余篇，其中影响因子大于 3.0 论文 50 余篇，SCI他引3000 余次，10篇论文被他引40次以上，其中单篇最高他引过百次。
近5年发表论文：
2015
1. Gold-Catalyzed Reductive Transformation of Nitro Compounds Using Formic Acid: Mild, Efficient, and Versatile, L. Yu, Q. Zhang, S. S. Li, J. Huang, Y. M. Liu, H. Y. He, Y. Cao*,ChemSusChem 2015, 8, 3029-3035. [PDF] [SI]
2. Formic Acid: A Versatile Renewable Reagent for Green ans Sustainable Chemical Syhthesis, X. Liu, S. S. Li, Y. M. Liu, Y. Cao*, Chin. J. Catal. 2015, 36, 1461-1475. [PDF]
3. Deoxygenative Coupling of Nitroarenes to Synthesize Aromatic Azo Compounds with CO Using Supported Gold Catalysts, H. Q. Li, X. Liu, Q. Zhang, S. S. Li, Y. M. Liu, Y. Cao*,Chem. Commun. 2015, 51, 11217-11220. [PDF] [SI]
4. Heterogeneous Gold-Catalyzed Selective Reductive Transformation of Quinolines with Formic Acid, L. Tao, Q. Zhang, S. S. Li, X. Liu, Y. M. Liu, Y. Cao*, Adv. Synth. Catal.2015, 357, 753-760. [PDF] [SI]
2014
1. An Aqueous Rechargeable Formate-based Hydrogen Battery Driven by Heterogeneous Pd Catalysis, Q. Y. Bi, J. D. Lin, Y. M. Liu, X. L. Du, H. Y. He, Y. Cao*, Angew. Chem. Int. Ed. 2014, 53, 13583-13587. [PDF] [SI]
2. Gold-catalyzed Direct Hydrogenative Coupling of Nitroarenes to Synthesize Aromatic Azo Compounds, X. Liu, H. Q. Li, S. Ye, Y. M. Liu, H. Y. He, Y. Cao*, Angew. Chem. Int. Ed.2014, 53,7624-7628. [PDF] [SI]
3. Gold Supported on Titania for Specific Monohydrogenation of Dinitroaromatics in the Liquid Phase, S. S. Liu, X. Liu, L.Yu, Y. M. Liu*, H. Y. He, Y. Cao*, Green Chem. 2014,16, 4162-4169. [PDF] [SI]
4. Partially Reduced Iridium Oxide Clusters Dispersed on Titania as Efficient Catalyst for Facile Synthesis of Dimethylformamide from CO2, H2 and Dimethylamine, Q. Y. Bi, J. D. Lin, Y. M. Liu, S. H. Xie, H. Y. He, Y. Cao*, Chem. Commun. 2014, 50, 9138-9140. [PDF] [SI]
5. Efficient and Exceptionally Selective Semireduction of Alkynes using a Supported Gold Catalyst under a CO Atmosphere, S. S. Li, X. Liu, Y. M. Liu*, H. Y. He, K. N. Fan, Y. Cao*,Chem. Commun. 2014, 50, 5626-5628. [PDF] [SI]
6. Propylene from Renewable Resources: Catalytic Conversion of Glycerol into Propylene, L. Yu, J. Yuan, Q. Zhang, Y. M. Liu, H. Y. He, K. N. Fan, Y. Cao*, ChemSusChem 2014, 7, 743-747. [PDF] [SI]
7. Supported Gold Catalysis: From Small Molecule Activation to Green Chemical Synthesis, X. Liu, L. He, Y. M. Liu, Y. Cao*, Acc. Chem. Res. 2014, 47, 793-804. [PDF]
2013
1. Efficient Catalytic Hydrogenolysis of Glycerol using Formic Acid as Hydrogen Source, J. Yuan, S. S. Li, L. Yu, Y. M. Liu, Y. Cao*, Chinese J. Catal. 2013, 34, 2066–2074. [PDF]
2. Catalytic Conversion of Biomass-derived Levulinic Acid into γ-valerolactone using Iridium Nanoparticles Supported on Carbon Nanotubes, X. L. Du, Y. M. Liu, J. Q. Wang, Y. Cao*, K. N. Fan, Chinese J. Catal. 2013, 34, 993–1001. [PDF]
3. Mild, Selective and Switchable Transfer Reduction of Nitroarenes Catalyzed by Supported Gold Nanoparticles, X. Liu, S. Ye, H. Q. Li, Y. M. Liu, Y. Cao*, K. N. Fan, Catal. Sci. Technol. 2013, 3, 3200-3206. [PDF] [SI]
4. C-C Cross-Coupling of Primary and Secondary Benzylic Alcohols using Supported Gold-Based Bimetallic Catalysts, X. Liu, R. S. Ding, L. He, Y. M. Liu, Y. Cao*, H. Y. He, K. N. Fan, ChemSusChem 2013, 6, 604-608. [PDF] [SI]
5. Sucrose-templated Mesoporous β-Ga2O3 as a Novel Efficient Catalyst for Dehydrogenation of Propane in the Presence of CO2, J. L. Wu, M. Chen, Y. M. Liu*, Y. Cao*, H. Y. He, K. N. Fan, Catal. Commun. 2013, 30, 61-65. [PDF]
6. A Versatile Aqueous Reduction of Bio-based Carboxylic Acids using Syngas as a Hydrogen Source, L. Yu, X. L. Du, J. Yuan, Y. M. Liu, Y. Cao*, H. Y. He, K. N. Fan,ChemSusChem 2013, 6, 42-46. [PDF] [SI]
7. Copper-based Catalysts for the Efficient Conversion of Carbohydrate Biomass into γ-valerolactone in the Absence of Externally Added Hydrogen, J. Yuan, S. S. Li, L. Yu, Y. M. Liu, Y. Cao*, H. Y. He, K. N. Fan, Energy Environ. Sci. 2013, 6, 3308-3313. [PDF] [SI]
2012
1. Tunable Copper-catalyzed Chemoselective Hydrogenolysis of Biomass-derived γ-valerolactone into 1,4-pentanediol or 2-methyltetrahydrofuran, X. L. Du, Q. Y. Bi, Y. M. Liu, Y. Cao* H. Y. He, K. N. Fan, Green Chem. 2012, 14, 935-939. [PDF] [SI]
2. Graphite Oxide as an Efficient and Durable Metal-free Catalyst for Aerobic Oxidative Coupling of Amines to Imines, H. Huang, J. Huang, Y. M. Liu*, H. Y. He, Y. Cao*, K. N. Fan, Green Chem. 2012, 14, 930-934. [PDF] [SI]
3. Highly Efficient Heterogeneous Gold-catalyzed Direct Synthesis of Tertiary and Secondary Amines from Alcohols and Urea, L. He, Y. Qian, R. S. Ding, Y. M. Liu, H. Y. He, K. N. Fan, Y. Cao*, ChemSusChem 2012, 5, 621-624. [PDF]
4. A General and Efficient Heterogeneous Gold-Catalyzed Hydration of Nitriles in Neat Water under Mild Atmospheric Conditions, Y. M. Liu, L. He, M. M. Wang, Y. Cao*, H. Y. He, K. N. Fan, ChemSusChem 2012, 5, 1392-1396. [PDF] [SI]
5. Efficient Subnanometric Gold-Catalyzed Hydrogen Generation via Formic Acid Decomposition under Ambient Conditions, Q. Y. Bi, X. L. Du, Y. M. Liu, Y. Cao*, H. Y. He, K. N. Fan, J. Am. Chem. Soc. 2012, 134, 8926-8933. [PDF] [SI]
6. An Unusual Chemoselective Hydrogenation of Quinoline Compounds using Supported Gold Catalysts, D. Ren, L. He, L. Yu, R. S. Ding, Y. M. Liu, Y. Cao*, H. Y. He, K. N. Fan,J. Am. Chem. Soc. 2012, 134, 17592-17598. [PDF] [SI]
2011
1. The Catalytic Use of Supported Gold Nanoparticles for Styrene Synthesis via Oxidative Dehydrogenation of Ethylbenzene, J. Xu, J. Huang, Y. M. Liu, Y. Cao*, Y. X. Li, K. N. Fan,Catal. Lett. 2011, 141, 198-206. [PDF]
2. Single-crystal-like Titania Mesocages, Z. F. Bian, J. Zhu, J. Wen, F. L. Cao, Y. N. Huo, X. F. Qian, Y. Cao, M. Q. Shen, H. X. Li, Y. F. Lu, Angew. Chem. Int. Ed. 2011, 50, 1105-1108. [PDF] [SI]
3. Dehydrogenation of Propane in the Presence of N2O over In2O3-Al2O3 Mixed Oxide Catalysts, M. Chen, J. L. Wu, Y. M. Liu, Y. Cao*, K. N. Fan, Catal. Commun. 2011, 12, 1063-1066. [PDF]
4. Mild and Efficient CO-mediated Eliminative Deoxygenation of Epoxides Catalyzed by Supported Gold Nanoparticles, J. Ni, L. He, Y. Cao*, H. Y. He, K. N. Fan, Chem. Commun. 2011, 47, 812-814. [PDF] [SI]
5. Gold Nanoparticles Supported on Hydroxylapatite as High Performance Catalysts for Low Temperature CO Oxidation, J. Huang, L. C. Wang, Y. M. Liu, Y. Cao*, H. Y. He, K. N. Fan, Appl. Catal. B: Environ. 2011, 101, 560-569. [PDF]
6. Highly Chemo- and Regioselective Transfer Reduction of Aromatic Nitro Compounds using Ammonium Formate Catalyzed by Supported Gold Nanoparticles, X. B. Lou, L. He, Y. Qian, Y. M. Liu, Y. Cao*, K. N. Fan, Adv. Synth. Catal. 2011, 353, 281-286.[PDF] [SI]
7. Direct One-pot Reductive N-alkylation of Nitroarenes using Alcohols with Supported Gold Catalysts, C. H. Tang, L. He, Y. M. Liu, Y. Cao*, H. Y. He, K. N. Fan, Chem. Eur. J. 2011,17, 7172-7177. [PDF] [SI]
8. Hydrogen-independent Reductive Transformation of Carbohydrate Biomass into γ-Valerolactone and Pyrrolidone Derivatives using Supported Gold Catalysts, X. L. Du, L. He, S. Zhao, Y. M. Liu, Y. Cao*, H. Y. He, K. N. Fan, Angew. Chem. Int. Ed. 2011, 50, 7815-7819. [PDF] [SI]
9. Direct One-pot Reductive Imination of Nitroarenes using Aldehydes and Carbon Monoxide by Titania Supported Gold Nanoparticles at Room Temperature, J. Huang, Lei Yu, L. He, Y. M. Liu, Y. Cao*, K. N. Fan, Green Chem. 2011, 13, 2672-2677. [PDF] [SI]
10. Titania Supported Iridium Subnanoclusters as an Efficient Heterogeneous Catalyst for Direct Synthesis of Quinolines from Nitroarenes and Aliphatic Alcohols, L. He, J. Q. Wang, Y. Gong, Y. M. Liu, Y. Cao*, H. Y. He, K. N. Fan, Angew. Chem. Int. Ed. 2011, 50, 10216-10220. [PDF] [SI]
11. Conversion of Biomass-derived Levulinate and Formate Esters into γ-valerolactone over Supported Gold Catalysts, X. L. Du, Q. Y. Bi, Y. M. Liu, Y. Cao*, K. N. Fan,ChemSusChem 2011, 4, 1838-1843. [PDF] [SI]
12. Gold Supported on Mesostructured Ceria as an Efficient Catalyst for the Chemoselective Hydrogenation of Carbonyl Compounds in Neat Water, M. M. Wang, L. He, Y. M. Liu, Y. Cao*, H. Y. He, K. N. Fan, Green Chem. 2011, 13, 602-607. [PDF]
2011年以后发表论文：
2010
1. Supported Indium Oxide as Novel Efficient Catalysts for Dehydrogenation of Propane with Carbon Dioxide, M. Chen, J. Xu, Y. M. Liu, Y. Cao*, H. Y. He, J. H. Zhuang*, Appl. Catal. A: Gen. 2010, 377, 35-41. [PDF]
2. A Novel Gold-catalyzed Chemoselective Reduction of α,β-unsaturated Aldehydes using CO and H2O as the Hydrogen Source, L. He, F. J. Yu, X. B. Lou, Y. Cao*, H. Y. He, K. N. Fan, Chem. Commun. 2010, 46, 1553-1555. [PDF] [SI]
3. Dehydrogenation of Propane over In2O3–Al2O3 Mixed Oxide in the Presence of Carbon Dioxide, M. Chen, J. Xu, Y. M. Liu, Y. Cao*, H. Y. He, J. H. Zhuang*, J. Catal. 2010, 272, 101-108. [PDF]
4. Synthesis of Novel Cage-like Mesoporous Vanadosilicate and Its Efficient Performance for Oxidation Dehydrogenation of Propane, Y. M. Liu*, S. H. Xie, Y. Cao*, H. Y. He, K. N. Fan, J. Phys. Chem. C 2010, 114, 5941-5946. [PDF]
5. Efficient and Clean Gold-catalyzed One-pot Selective N-Alkylation of Amines with Alcohols, L. He, X. B. Lou, J. Ni, Y. M. Liu, Y. Cao*, H. Y. He, K. N. Fan, Chem. Eur. J.2010, 16, 13965-13969. [PDF] [SI]
6. Facile Synthesis of Highly Stable and Well-dispersed Mesoporous ZrO2 Carbon Composites with High Performance in Oxidative Dehydrogenation of Ethylbenzene, Q. Li, J. Xu, Z. X. Wu, Dan Feng, J. P. Yang, J. Wei, Q. L. Wu, B. Tu, Y. Cao, D. Y. Zhao, Phys. Chem. Chem. Phys. 2010, 12, 10996–11003. [PDF]
2009
1. Gold Nanoparticles Supported on Manganese Qxides for Low Temperature CO Oxidation, L. C. Wang, Q. Liu, X. S. Huang, Y. M. Liu, Y. Cao*, K. N. Fan, Appl. Catal. B: Environ.2009, 88, 204-212. [PDF]
2. Dry Citrate-precursor Synthesized Nanocrystalline Cobalt Oxide as Highly Active Catalyst for Total Oxidation of Propane, Q. Liu, L. C. Wang, M. Chen, Y. Cao*, H. Y. He, K. N. Fan,J. Catal. 2009, 263, 104-113. [PDF]
3. Morphology Effects of Nanoscale Ceria on the Activity of Au/CeO2 Catalysts for Low-temperature CO Oxidation, X. S. Huang, H. Sun, L. C. Wang, Y. M. Liu*, K. N. Fan, Y. Cao*, Appl. Catal. B: Environ. 2009, 90, 224-232. [PDF]
4. A Green and Efficient Oxidation of Alcohols by Supported Gold Catalysts using Aqueous H2O2 under Organic Solvent-free Conditions, J. Ni, W. J. Yu, L. He, H. Sun, Y. Cao*, H. Y. He, K. N. Fan, Green Chem. 2009, 11, 756-759. [PDF][SI]
5. Effect of Pretreatment Atmosphere on CO Oxidation over α-Mn2O3 Supported Gold Catalysts, L. C. Wang, L. He, Y. M. Liu, Y. Cao*, H. Y. He, K. N. Fan, J. H. Zhuang*, J. Catal. 2009, 264, 145-153. [PDF]
6. Gold Supported on Hydroxyapatite as Versatile Multifunctional Catalyst for the Direct Tandem Synthesis of Imines and Oximes, H. Sun, F. Z. Su, J. Ni, Y. Cao*, H. Y. He, K. N. Fan, Angew. Chem. Int. Ed. 2009, 48, 4390-4393. [PDF] [SI]
7. Photooxygenation of Hydrocarbons over Efficient and Reusable Decatungstate Heterogenized on Hydrophobically Modified Mesoporous Silica, L. L. Ni, J. Ni, Y. Lv, P. Yang*, Y. Cao*, Chem. Commun. 2009, 2171-2173. [PDF] [SI]
8. 精细化学品绿色合成中的纳米Au催化：机遇与挑战, 何林, 倪吉, 孙浩, 曹勇, 催化学报，2009, 30, 958-964. [PDF]
9. Highly Selective Ce-Ni-O Catalysts for Efficient Low Temperature Oxidative Dehydrogenation of Propane, Y. M. Liu, L. C. Wang, M. Chen, J. Xu, Y. Cao*, H. Y. He, K. N. Fan, Catal. Lett. 2009, 130, 350-354. [PDF]
10. The Role of the Promoters in Cu Based Catalysts for Methanol Steam Reforming, G. S. Wu, D. S. Mao, G. Z. Lu, Y. Cao*, K. N. Fan, Catal. Lett. 2009, 130, 177-184. [PDF]
11. Aqueous Room Temperature Gold-catalyzed Chemoselective Transfer Hydrogenation of Aldehydes, L. He, J. Ni, L. C. Wang, F. J. Yu, Y. Cao*, H. Y. He, K. N. Fan, Chem. Eur. J.2009, 15, 11833-11836. [PDF] [SI]
12. Efficient Room Temperature Gold-catalyzed Selective Reduction of Nitro Compounds using CO and H2O as the Hydrogen Source, L. He, L. C. Wang, H. Sun, J. Ni,Y. Cao*, H. Y. He, K. N. Fan, Angew. Chem. Int. Ed. 2009, 48, 9538-9541. [PDF] [SI]
13. Mesostructured CeO2as an Effective Catalyst for Styrene Synthesis by Oxidative Dehydrogenation of Ethylbenzene, J. Xu, L. C. Wang, Y. M. Liu, Y. Cao*, H. Y. He, K. N. Fan, Catal. Lett. 2009,133, 307-313. [PDF]
14. Vanadia Supported on H2O2 -detemplated Mesoporous SBA-15 as New Effective Catalysts for the Oxidative Dehydrogenation of Propane, J. Xu, M. Chen, Y. M. Liu, Y. Cao*, H. Y. He, K. N. Fan*, Micro. Meso. Mat. 2009, 118, 354-360. [PDF]
2008
1. Ga-Al Mixed-Oxide-Supported Gold Nanoparticles with Enhanced Activity for Aerobic Alcohol Oxidation, F. Z. Su, Y. M. Liu, L. C. Wang, Y. Cao*, H. Y. He, K. N. Fan, Angew. Chem. Int. Ed. 2008, 47, 334-337. [PDF] [SI]
2. Aerobic Oxidation of Alcohols Catalyzed by Gold Nanoparticles Supported on Gallia Polymorphs, F. Z. Su, M. Chen, L. C. Wang, X. S. Huang, Y. M. Liu, Y. Cao*, H. Y. He, K. N. Fan, Catal. Commun. 2008, 9, 1027-1032. [PDF]
3. Waste-free Soft Reactive Grinding Synthesis of High-surface-area Copper-manganese Spinel Oxide Catalysts Highly Effective for Methanol Steam Reforming, Q. Liu, L. C. Wang, Y. M. Liu, Y. Cao*, H. Y. He, K. N. Fan, Catal. Lett. 2008, 121, 144-150. [PDF]
4. Simple Fabrication of Thermally Stable Apertured N-doped TiO2 Microtubes as a Highly Efficient Photocatalyst under Visible Light Irradiation, J. H. Xu, W. L. Dai, J. X. Li, Y. Cao, H. X. Li, H. Y. He, K. N. Fan, Catal. Commun. 2008, 9, 146-152. [PDF]
5. Simple Fabrication of Twist-like Helix N,S-codoped Titania Photocatalyst with Visible-light Response, J. H. Xu, J. X. Li, W. L. Dai, Y. Cao, H. X. Li, K. N. Fan, Appl. Catal. B: Environ. 2008, 79, 72-80. [PDF]
6. Novel Core-shell Structured Mesoporous Titania Microspheres: Preparation, Characterization and Excellent Photocatalytic Activity in Phenol Abatement, J. H. Xia, W. L. Dai, J. X. Li, Y. Cao, H. X. Li, K. N. Fan, J. Photochem. Photobiol. A, Chem. 2008, 195, 284–294 [PDF]
7. MnO2 Nanorod Supported Gold Nanoparticles with Enhanced Activity for Solvent-free Aerobic Alcohol Oxidation, L. C. Wang, Y. M. Liu, M. Chen, Y. Cao*, H. Y. He, K. N. Fan,J. Phys. Chem. C 2008, 112, 6981-6987. [PDF]
8. Solvent-free Selective Oxidation of Alcohols by Molecular Oxygen over β-MnO2 Nanorods Supported Gold Nanoparticles, L. C. Wang, L. He, Q. Liu, Y. M. Liu, M. Chen, Y. Cao*, H. Y. He, K. N. Fan, Appl. Catal. A: Gen. 2008, 344, 150-157. [PDF]
9. Dehydrogenation of Propane over Spinel-type Gallia-alumina Solid Solution Catalysts, M. Chen, F. Z. Su, J. Xu, Y. M. Liu, Y. Cao*, H. Y. He, K. N. Fan, J. Catal. 2008, 256, 293-300. [PDF]
10. Enhanced Activity of Spinel-type Ga2O3–Al2O3 Mixed Oxide for the Dehydrogenation of Propane in the Presence of CO2 , M. Chen, J. Xu, Y. M. Liu, Y. Cao*, H. Y. He, K. N. Fan,Catal. Lett. 2008, 124, 369-375. [PDF]
11. Aluminum Containing MCF Silica as Highly Efficient Solid Acid Catalyst for Alcohol Esterification, Y. M. Liu, J. Xu, L. C. Wang, Y. Cao*, H. Y. He, K. N. Fan, Catal. Lett. 2008,125, 62-68. [PDF]
12. Efficient and Chemoselective Reduction of Carbonyl Compounds with Supported Gold Catalysts under Transfer Hydrogenation Conditions, F. Z. Su, L. He, J. Ni, Y. Cao*, H. Y. He, K. N. Fan, Chem. Commun. 2008, 3531-3533. [PDF] [SI]
13. Gold Supported on Nanocrystalline β-Ga2O3 as Versatile Bifunctional Catalyst for Facile Oxidative Transformation of Alcohols, Aldehydes and Acetals into Esters, F. Z. Su, J. Ni, H. Sun, Y. Cao*, H. Y. He, K. N. Fan, Chem. Eur. J. 2008, 14, 7131-7135. [PDF] [SI]
14. Gold Nanoparticles Deposited on Manganese (III) Oxide as Novel Efficient Catalyst for Low Temperature CO Oxidation, L. C. Wang, X. S. Huang, Q. Liu, Y. M. Liu, Y. Cao*, H. Y. He, K. N. Fan, J. H. Zhuang*, J. Catal. 2008, 259, 66-74. [PDF]
15. Facile Synthesis of Fe-loaded Mesoporous Silica by a Combined Detemplation-incorporation Process through Fenton’s Chemistry, Y. M. Liu, J. Xu, L. He, Y. Cao*, H. Y. He, D. Y. Zhao, J. H. Zhuang*, K. N. Fan, J. Phys. Chem. C2008, 112, 16575-16583. [PDF]
2007
1. An Integrated Low Temperature Approach to Highly Photoactive Nanocrystalline Mesostructured Titania, J. Zhu, Z. F. Bian, J. Ren, Y. Cao*, Y. M. Liu, W. L. Dai, H. Y. He, K. N. Fan, Catal. Commun. 2007, 8, 971-976. [PDF]
2. Production of Hydrogen by Steam Reforming of Methanol over Cu/ZnO Catalysts Prepared via a Practical Soft Reactive Grinding Route Based on Dry Oxalate-precursor Synthesis, L. C. Wang, Y. M. Liu, M. Chen, Y. Cao*, H. Y. He, G. S. Wu, W. L. Dai, K. N. Fan, J. Catal. 2007, 246, 193-204. [PDF]
3. 高性能纳米金催化剂的研究进展, 王路存, 苏方正, 黄新松, 曹勇, 石油化工, 2007, 9, 867-873.
4. 选择氧化中新型Keggin结构硅钨酸盐催化剂的研究进展, 李静霞, 戴维林, 曹勇, 范康年, 石油化工, 2007, 4, 412-417.
5. Microwave Accelerated Solvent-free Aerobic Oxidation of Benzyl Alcohol over Efficient and Reusable Manganese Oxides, Y. Su, L. C. Wang, Y. M. Liu, Y. Cao*, H. Y. He, K. N. Fan,Catal. Commun. 2007, 8, 2181-2185. [PDF]
6. Nanocrystalline Anatase TiO2 Photocatalysts Prepared via a Facile Low Temperature Nonhydrolytic Sol-gel Reaction of TiCl4 and Benzyl Alcohol, J. Zhu, J. Yang, Z. F. Bian, J. Ren, Y. M. Liu, Y. Cao*, H. X. Li, H. Y. He, K. N. Fan*, Appl. Catal. B: Environ. 2007, 76, 82-91. [PDF]
7. New Green Catalytic Manufacture of Glutaric Acid from the Oxidation of Cyclopentane-1,2-diol with Aqueous Hydrogen Peroxide, H. Chen, W. L. Dai, R. H. Gao, Y. Cao*, H. X. Li, K. N. Fan, Appl. Catal. A: Gen. 2007,328, 226-236. [PDF]
8. A Green Pocess For O-heterocyclization of Cycloocta-1,5-diene by Peroxotungstic Species with Aqueous H2O2, R. H. Gao, W. L. Dai, Y. Y. Le, X. L. Yang, Y. Cao, H. X. Li, K. N. Fan, Green Chem. 2007, 9, 878-881. [PDF]
9. Structural Evolution and Catalytic Properties of Nanostructured Cu/ZrO2 Catalysts Prepared by Oxalate Gel-coprecipitation Technique, L. C. Wang, Q. Liu, M. Chen, Y. M. Liu, Y. Cao*, H. Y. He, K. N. Fan, J. Phys. Chem. C2007, 111, 16549-16557. [PDF]
10. Production of hydrogen by steam reforming of methanol over Cu/ZnO catalysts prepared via a practical soft reactive grinding route based on dry oxalate-precursor synthesis, L. C. Wang, Y. M. Liu, Y. Cao*, G. S. Wu, C. Z. Yao, W. L. Dai, H. Y. He, K. N. Fan,J. Catal.2007, 246, 193-204. [PDF]
2006
1. Chromium Supported on Mesocellular Silica Foam (MCF) for Oxidative Dehydrogenation of Propane, Y. M. Liu, W. L. Feng, L. C. Wang, Y. Cao, W. L. Dai, H. Y. He, K. N. Fan,Catal. Lett. 2006, 106, 145-152. [PDF]
2. Highly Effective Hydrogen Production from Steam Reforming of Methanol over SBA-15-Promoted Cu/ZnO/Al2O3 Catalysts, C. Z. Yao, X. R. Zhang, L. C. Wang, Y. Cao, W. L. Dai, K. N. Fan, D. Wu, Y. H. Sun, Acta Chimica Sinica2006, 64, 269-272. [PDF]
3. Structure and Catalytic Properties of Vanadium Oxide Supported on Mesocellulous Silica Foams (MCF) for the Oxidative Dehydrogenation of Propane to Propylene, Y. M. Liu, W. L. Feng, T. C. Li, H. Y. He, W. L. Dai, Y. Cao*, K. N. Fan, J. Catal. 2006, 239, 125-136. [PDF]
4. A Low Temperature Benzyl Alcohol Alcoholysis Approach to Highly Photoactive Nanocrystalline Anatase TiO2, J. Zhu, J. Yang, L. Chen, Y. Cao, W. L. Dai, K. N. Fan, Chinese J. Catal. 2006, 27, 171-177.
5. Transformation of Various Oxygen Species on the Surface of Electrolytic Silver Characterized by in Situ Raman Spectroscopy, L. P. Ren, W. L. Dai, X. L. Yang, Y. Cao, Z. K. Xie, K. N. Fan, Chinese J. Catal. 2006, 27, 115-118. [PDF]
6. Highly Photoactive Nanocrystalline TiO2 Aerogel Synthesized by a Facile Epoxide-mediated Non-alkoxide Sol-gel Method, L. Chen, J. Zhu, J. Yang, Y. M. Liu, Y. Cao, Y. M. Liu, H. Y. He, W. L. Dai, K. N. Fan, Chinese J. Catal. 2006, 27, 291-293.
7. On the Role of Reverse Hydrogen and Water Spillover for Methanol Decomposition over Cu/ZrO2 Catalyst, G. S. Wu, L. C. Wang, Y. M. Liu, Y. Cao, W. L. Dai, H. Y. He, K. N. Fan,Acta Chimica Sinica2006, 64, 1017-1021.
8. Implication of the Role of Oxygen Anions and Oxygen Vacancies for Methanol Decomposition over Zirconia Supported Copper Catalysts, G. S. Wu, L. C. Wang, Y. M. Liu, Y. Cao*, W. L. Dai, H. Y. He, K. N. Fan*, Appl. Surf. Sci. 2006, 253, 974-982. [PDF]
9. Photocatalytic Activity of Epoxide Sol-gel Derived Titania Transformed into Nanocrystalline Aerogel Materials by Supercritical Drying, L. Chen, J. Zhu, Y. M. Liu,Y. Cao*, H. X. Li, W. L. Dai, H. Y. He, K. N. Fan, J. Mol. Catal. A, Chem. 2006, 255, 260-268. [PDF]
10. Studies on the Structural Change of a Reaction-controlled Phase-transfer [p-C5H5NC16H33]3 {PO4[WO3]4} Catalyst during the Selective Oxidation of Cyclopentene to Glutaric Acid with Aqueous H2O2, H. Chen, W. L. Dai, X. L. Yang, R. H. Gao, Y. Cao, H. X. Li, K. N. Fan, Appl. Catal. A: Gen. 2006, 309, 62-69. [PDF]
11. Tungsten Containing MCF Silica as Active and Recyclable Catalysts for Liquid-phase Oxidation of 1,3-butanediol to 4-hydroxy-2-butanone, Y. Su, Y. M. Liu, L. C. Wang, M. Chen, Y. Cao*, W. L. Dai, H. Y. He, K. N. Fan*, Appl. Catal. A: Gen. 2006, 315, 91-100. [PDF]
12. Effect of Preparation Method on the Hydrogen Production from Methanol Steam Reforming over Binary Cu/ZrO2 Catalysts, C. Z. Yao, L. C. Wang, Y. M. Liu, G. S. Wu, Y. Cao*, W. L. Dai, H. Y. He, K. N. Fan*, Appl. Catal. A: Gen. 2006, 297, 151-158. [PDF]
13. 环戊烯选择氧化合成戊二酸绿色催化过程, 陈慧, 戴维林, 高瑞华, 杨新丽, 曹勇, 范康年, 石油化工, 2006, 35, 118-121.
2005
1. Synthesis, Characterization and Catalytic Application of Mesoporous W-MCM-48 for the Selective Oxidation of Cyclopentene to Glutaraldehyde, X. L. Yang , W. L. Dai, R. H. Gao, H. Chen, H. X. Li, Y. Cao, K. N. Fan, J. Mol. Catal. A-Chem. 2005, 241, 205-214. [PDF]
2. Novel Tungsten-containing Mesoporous HMS Material: Its Synthesis, Characterization and Catalytic Application in the Selective Oxidation of Cyclopentene to Glutaraldehyde by Aqueous H2O2, X. L. Yang, W. L. Dai, J. H. Xu, Y. Cao, H. X. Li, K. N. Fan, Appl. Catal. A: Gen. 2005, 283, 1-8. [PDF]
3. Highly Efficient Ni-Ce-O Mixed Oxide Catalysts via Gel-coprecipitation of Oxalate Precursors for Catalytic Combustion of Methane, N. Yi, Y. Cao, Y. M. Liu, W. L. Dai, H. Y. He, K. N. Fan, Chem. Lett. 2005, 34, 108-109.
4. Microwave-irradiation Promoted Cu/ZnO/Al2O3 Catalyst for Hydrogen Production from Steam Reforming of Methanol, X. R. Zhang, C. Z. Yao, L. C. Wang, Y. Cao, D. Wu, Y. H. Sun, W. L. Dai, K. N. Fan, Chem. J. Chin. Univ.-Chin. 2005, 26, 1137-1139.
5. Gas-phase Photo-oxidations of Organic Compounds over Different forms of Zirconia, C. Y. Wu, X. P. Zhao, Y. J. Ren, Y. H. Yue, W. M. Hua, Y. Cao, Y. Tang, Z. Gao, J. Mol. Catal. A, Chem. 2005, 229, 233–239. [PDF]
6. Carbon Exchange between Methane and Carbon Dioxide over Rh/H-BEA, L. P. Qian, Y. Cao, B. Yue, Yu Ren, B. L. Chen, H. Y. He, Chinese J. Catal. 2005, 26, 455-457. [PDF]
7. A Highly Efficient Cu/ZnO/Al2O3 Catalyst via Gel-coprecipitation of Oxalate Precursors for Low-temperature Steam Reforming of Methanol, X. R. Zhang, L. C. Wang, C. Z. Yao, Y. Cao*, W. L. Dai, H. Y. He, K. N. Fan, Catal. Lett. 2005, 102, 183-190. [PDF]
8. Synthesis of Novel Core-shell Structured WO3/TiO2 Spheroids and Its Application in the Catalytic Oxidation of Cyclopentene to Glutaraldehyde by Aqueous H2O2, X. L. Yang, W. L. Dai, C. W. Guo, Chen H, Y. Cao, H. X. Li, H. Y. He, K. N. Fan, J. Catal. 2005, 234, 438-450. [PDF]
9. Nanocrystalline LaCoO3 Perovskites Confined in SBA-15 Silica as New Efficient Catalysts for Hydrocarbon Oxidation, N. Yi, Y. Cao*, Y. Su, W. L. Dai, H. Y. He, K. N. Fan*, J. Catal.2005, 230, 249-253. [PDF]
10. A Unique Microwave Effect on the Microstructural Modification of Cu/ZnO/Al2O3Catalysts for Steam Reforming of Methanol, X. R. Zhang, L. C. Wang, Y. Cao*, W. L. Dai, H. Y. He, K. N. Fan*, Chem. Commun. 2005, 32, 4104-4106. [PDF] [SI]
11. Direct Dehydrogenation of Methanol to Formaldehyde over Pre-treated Polycrystalline Silver Catalyst, L. P. Ren, W. L. Dai, X. L. Yang, J. H. Xu, Y. Cao, H. X. Li, K. N. Fan,Catal. Lett. 2005, 99, 83-87. [PDF]
12. 新型铀基催化剂的研究进展, 高瑞华, 戴维林, 杨新丽, 曹勇, 范康年, 石油化工, 2005, 34, 791-796.
13. 新型WO3/HMS催化剂的合成及其在环戊烯选择氧化反应中的性能研究, 杨新丽, 戴维林, 徐建华, 陈浩, 曹勇, 范康年, 催化学报, 2005, 26, 311-316.
2004
1. A Density Functional Theory Study on the Adsorption of Chlorobenzene on the Si(111)-7 × 7 Surface, Z. H. Li, Y. C. Li, W. N. Wang, Y. Cao, K. N. Fan, J. Phys. Chem. B 2004, 108, 14049-14055. [PDF]
2. Novel Highly Active Ag-SiO2-Al2O3-ZnO Catalyst for the Production of Anhydrous HCHO from Direct Dehydrogenation of CH3OH, L. P. Ren, W. L. Dai, X. L. Yang, Y. Cao, K. N. Fan, Appl. Catal. A: Gen. 2004, 273, 83-88. [PDF]
3. Novel Efficient and Green Approach to the Synthesis of Glutaraldehyde over Highly Active W-doped SBA-15 Catalyst, X. L. Yang, W. L. Dai, H. Chen, Y. Cao, H. X. Li, H. Y. He, K. N. Fan, J. Catal. 2004, 229, 259-263.[PDF]
4. Synthesis and Characterization of Thermally Stable Mesostructured Sulfated Zirconia by a Novel Sulfate-assisted Alcohothermal Route, N. Yi, Y. Cao*, W. L. Feng, W. L. Dai, K. N. Fan, Catal. Lett. 2004, 99, 73-78. [PDF]
5. Catalytic Oxidation of Methane over Novel Ce-Ni-O Mixed Oxide Catalysts Prepared by Oxalate Gel-coprecipitation, N. Yi, Y. Cao*, W. L. Feng, W. L. Dai, K. N. Fan, Catal. Lett.2004, 99, 207-213. [PDF]
6. Highly Effective Hydrogen Production from Steam Reforming of Methanol over Cu/ZnO/Al2O3 Catalysts Promoted by Nanostructured Carbon Materials, X. R. Zhang, L. C. Wang, C. Z. Yao, Y. Cao, W. L. Dai, K. N. Fan, Chem. J. Chin. Univ.-Chin. 2004, 25, 2125-2127.
7. Effect of Promoter on the Structure and Performance of Activated Carbon-supported Wacker-type Catalyst for DMC Synthesis, P. Yang, Y. Cao, X. H. Bao, W. L. Dai, K. N. Fan, Chinese J. Catal. 2004, 25, 995-999.
8. A Remarkable Effect of Alkali Addition in the Oxidative Carbonylation of Methanol to Dimethyl Carbonate Catalyzed by a Polymer-complexed Cu(II) Catalyst System, W. L. Feng, Y. Cao*, N. Yi, W. L. Dai, K. N. Fan*, Chem. Lett. 2004, 33, 958-959. [PDF]
9. Direct Production of Hydrogen Peroxide from CO, O2, and H2O Over a Novel Alumina Supported Cu Catalyst, W. L. Feng, Y. Cao*, N. Yi, W. L. Dai, K. N. Fan*, New J. Chem.2004, 28, 14311-14333. [PDF]
10. Ni-Ce-O Mixed Oxide via Gel-coprecipitation of Oxalate Precursors for Catalytic Combustion of Methane, N. Yi, Y. Cao, W. L. Dai, H. Y. He, K. N. Fan, Chinese J. Catal.2004, 26 (1), 7-9.
11. Ag-SiO2-Al2O3 Composite as Highly Active Catalyst for the Formation of Formaldehyde from Partial Oxidation of Methanol, W. L. Dai, Y. Cao, L. L. Ren, X. L. Yang, J. H. Xu, H. Y. He, K. N. Fan, J. Catal. 2004, 228, 80-91. [PDF]
12. Vanadium Oxide Supported on Mesoporous SBA-15 as Highly Selective Catalysts in the Oxidative Dehydrogenation of Propane, Y. M. Liu, Y. Cao*, N. Yi, W. L. Feng, W. L. Dai, S. R. Yan, H. Y. He, K. N. Fan*, J. Catal. 2004, 224, 417-428. [PDF]
13. Impact of Preparation Strategy on the Properties of Carbon-supported Wacker-type Catalysts in Vapor-phase Dimethyl Carbonate Synthesis, Y. Cao*, P. Yang, C. Z. Yao, N. Yi, W. L. Feng, W. L. Dai, K. N. Fan*, Appl. Catal. A: Gen. 2004, 272, 15-22. [PDF]
14. A Novel Non-phosgene Process for the Synthesis of Methyl N-phenyl Carbamate from Methanol and Phenylurea, Effect of Solvent and Catalyst, X. K. Wang, S. R. Yan, Y. Cao, K. N. Fan, H. Y. He, M. Q. Kang, S. Y. Peng, Chinese J. Chem. 2004, 22, 782-786.
15. 纳米氧化铈催化苯甲酸甲酯催化氢化合成苯乙酮, 王少成, 陈庚, 曹勇, 沈伟, 胡建国,徐华龙, 复旦学报, 2004, 43, 615-620. [PDF]
16. 新型介孔钒氧化物催化剂上丙烷高选择性氧化脱氢制丙烯研究, 伊楠, 刘永梅, 冯伟樑,曹勇, 戴维林, 范康年, 吴东, 孙予罕, 复旦学报, 2004, 43, 597-602. [PDF]
17. 新型MCM-41固载化铌酸催化氧化环戊烯制备戊二醛, 徐建华, 戴维林, 杨新丽, 曹勇,范康年, 化学学报, 2004, 62, 1467-1471. [PDF]
2003
1. Multiple Configurations of N-methylpyrrole Binding on Si(111)-7×7, F. Tao, Z. L. Yuan, X. F. Chen, M. H. Qiao, Z. H. Wang, Y. J. Dai, H. G. Huang, Y. Cao, G. Q. Xu, Phys. Rev. B2003, 67, 245406. [PDF]
2. Novel Highly Active Ag-SiO2-MgO Catalysts used for Direct Dehydrogenation of Methanol to Anhydrous Formaldehyde, L. P. Ren, W. L. Dai, Y. Cao, K. N. Fan, Catal. Lett. 2003,85, 81-85.
3. Dissociative Adsorption of Pyrrole on Si(111)-(7×7), Z. L. Yuan, X. F. Chen, Z. H. Wang, Y. Cao, K. S. Yong, Q. P. Liu, G. Q. Xu, J. Chem. Phys. 2003, 119, 10389-10395.
4. Preparation of High Performance Cu/ZnO/Al2O3 Catalyst for Methanol Synthesis from CO2Hydrogenation by Coprecipitation-reduction, Y. Cao, L. F. Chen，W. L. Dai, K. N. Fan, D. Wu，Y. H. Sun, Chem. J. Chin. Univ.-Chin. 2003, 24, 1296-1298.
5. Novel Economic and Green Approach to the Synthesis of Highly Active W-MCM41 in Oxidative Cleavage of CPE, W. L. Dai, H. Chen, H. X. Li, Y. Cao, K. N. Fan, Chem. Commun. 2003, 892-893. [PDF]
6. Amperometric Biosensor Based on a Nanoporous ZrO2 Matrix, B. H. Liu, Y. Cao, Ddadan Chen, J. L. Kong, J. Q. Deng, Anal. Chim. Acta. 2003, 478, 59-66. [PDF]
7. First Observation of Highly Efficient Dehydrogenation of Methanol to Anhydrous Formaldehyde over Novel Ag-SiO2-MgO-Al2O3 Catalyst, L. P. Ren, W. L. Dai, Y. Cao, H. X. Li, K. N. Fan, Chem. Commun. 2003, 3030-3031. [PDF]
8. Fabrication of Mesoporous Core-shell Structured Titania Microspheres with Hollow Interiors, C. W. Guo, Y. Cao*, S. H. Xie, W. L. Dai, K. N. Fan, Chem. Commun. 2003,700-701. [PDF]
9. Adsorption and Thermal Dissociation of Pyrrole on Si(100)-2×1, M. H. Qiao, F. Tao,Y. Cao, G. Q. Xu, Surf. Sci. 2003, 544, 285-294. [PDF]
10. 45. Mesoporous Bimetallic PdCl2-CuCl2 Catalysts for Dimethyl Carbonate Synthesis by Vapor Phase Oxidative Carbonylation of Methanol, P. Yang, Y. Cao, J. C. Hu, W. L. Dai, K. N. Fan, Appl. Catal. A: Gen. 2003, 241, 363-373. [PDF]
11. Effect of Chemical Treatment of Activated Carbon as a Support for Promoted Dimethyl Carbonate Synthesis by Vapor Phase Oxidative Carbonylation of Methanol over Wacker-type Catalysts, P. Yang, Y. Cao, W. L. Dai, J. F. Deng, K. N. Fan, Appl. Catal. A: Gen.2003, 243, 323-331. [PDF]
12. Highly Effective Oxidative Dehydrogenation of Propane over Vanadia Supported on Mesoporous SBA-15 Silica, Y. M. Liu, Y. Cao, W. L. Dai, K. N. Fan, Catal. Lett. 2003, 88, 61-67. [PDF]
13. CuCl Catalyst Heterogenized on Diamide Immobilized SBA-15 for Efficient Oxidative Carbonylation of Methanol to Dimethylcarbonate, Y. Cao*, J. C. Hu, P. Yang, W. L. Dai, K. N. Fan*, Chem. Commun. 2003, 908-909. [PDF] [SI]
14. The Non-isothermal Decomposition Kinetics of Copper(II) Complexes with Phthalanilic Acids and Amino Acids, L. P. Ren, W. L. Dai, H. X. Li, Y. Cao, X. H. Zhang, K. N. Fan, Int. J. Chem. Kinet. 2003, 35, 623-628.
15. 表征固体超强酸性的新方法——正丁烷异构化反应的原位13C MAS NMR谱, 马卓娜, 胡军成, 范康年, 曹勇, 贺鹤勇, 高滋, 化学学报, 2003, 61, 1352-1356. [PDF]
16. 纳米Ni-Co-B非晶态合金抗氧化行为的原位XPS研究, 戴维林, 曹勇, 范康年, 邓景发, 高等学校化学学报, 2003, 3, 473-476. [PDF]
17. 规则中孔TiO2微球的均相沉淀合成及其在环戊烯氧化反应中的应用, 郭昌文, 戴维林,曹勇, 范康年, 高等学校化学学报, 2003, 24, 1097-1099. [PDF]
18. 氧在银/二氧化硅催化剂上的超高真空程序升温脱附研究, 任丽萍, 戴维林, 董义, 乔明华, 曹勇, 范康年, 李和兴, 催化学报, 2003, 24, 669-673. [PDF]
19. W-SBA-15的原位合成及其在环戊烯氧化反应中的催化性能研究, 郭昌文, 戴维林, 曹勇,范康年, 化学学报, 2003, 61, 1496-1499. [PDF]
20. 甲醇脱氢制无水甲醛的高活性Ag-SiO2-Al2O3催化剂, 任丽萍, 戴维林, 曹勇, 李和兴, 章文华, 范康年, 化学学报, 2003, 61, 937-940. [PDF]
2002
1. Highly Efficient VOx/SBA-15 Mesoporous Catalysts for Oxidative Dehydrogenation of Propane, Y. M. Liu, Y. Cao*, K. K. Zhu, S. R. Yan, W. L. Dai, H. Y. He, K. N. Fan*, Chem. Commun. 2002, 2832-2833. [PDF]
2. A Novel Homogeneous Catalyst Made of Poly(N-vinyl-2-pyrrolidone)-CuCl2Complex for the Oxidative Carbonylation, J. C. Hu, Y. Cao, P. Yang, J. F. Deng, K. N. Fan, J. Mol. Catal. Chem. A 2002, 185, 1-9. [PDF]
3. Evidence for the Anti-oxidation Effect of Boron on the Ultra-fine Ni-B Amorphous Alloy Catalyst, W. L. Dai, H. X. Li, Y. Cao, M. H. Qiao, K. N. Fan, J. F. Deng, Langmuir 2002,18, 9605-9608. [PDF]
4. In Situ Raman Studies on the Interaction of Oxygen and Methanol with Iodine-modified Electrolytic Silver Catalyst, W. L. Dai, Y. Dong, Y. Cao, K. N. Fan, J. F. Deng, Y. Y. Liao, B. F. Hong, J. Raman Spectr. 2002, 33, 318-324. [PDF]
5. TBAB-modified Heterogeneous Wacker-type Catalysts for Highly Selective Oxidative Carbonylation of Methanol to Dimethyl Carbonate, S. C. Wang, Y. Cao, P. Yang, J. G. Hu, D. Wu, Y. H. Sun, J. F. Deng, Chem. J. Chin. Univ.-Chin. 2002, 12, 2363-2365.
6. A Novel Method to Prepare Cu/ZnO/Al2O3 Methanol Synthesis Catalyst, Z. S. Hong, Y. Cao, J. F. Deng, K. N. Fan, Chem. J. Chin. Univ.-Chin. 2002, 23, 706-708.
7. 苯在Si(111)-7×7表面化学吸附的理论研究, 李燕茶, 王文宁, 曹勇,范康年, 化学学报, 2002,60, 653-659. [PDF]
8. A Convenient Alcohothermal Approach for Low Temperature Synthesis of CuO Nanoparticles, Z. S. Hong, Y. Cao, J. F. Deng, Mater. Lett. 2002, 52, 34-38. [PDF]
9. CO2 Hydrogenation to Methanol over Cu/ZnO/Al2O3 Catalysts Prepared by a Novel Gel-network-coprecipitation, Z. S. Hong, Y. Cao, J. F. Deng, K. N. Fan, Catal. Lett. 2002, 82, 37-44. [PDF]
10. Rare Earth (Y, La, Ce)-promoted V-HMS Mesoporous Catalysts for Oxidative Dehydrogenation of Propane, R. Zhou, Y. Cao, S. R. Yan, K. N. Fan, Appl. Catal. A: Gen.2002, 236, 103-111. [PDF]
11. 酰胺基改性的介孔MCM-41锚定Cu(II)杂化材料的合成和表征, 胡军成, 曹勇, 杨平, 邓景发, 范康年, 复旦学报, 2002, 41, 320-324.
12. 焙烧条件对Cu/ZnO/Al2O3甲醇催化剂的影响, 洪中山, 曹勇, 孙崎, 邓景发, 范康年, 复旦学报,2002, 41, 330-334.
13. 负载型Ni-B非晶态合金的制备及其催化加氢活性研究, 刘波, 陈雪莹, 庄继华, 乔明华,曹勇, 朱源龙, 贺鹤勇, 范康年, 复旦学报, 2002, 41, 424-428.
曹勇，教授，博士生导师，男，1973年出生。1995年毕业于复旦大学化学系物理化学专业，获理学学士学位。1998至2000年间于新加坡国立大学化学系攻读联合培养博士学位，2000年7月毕业于复旦大学化学系物理化学专业获理学博士学位并留校任教至今。2001年11月破格晋升为复旦大学副教授，同年起升任硕士生导师。2005年1月破格晋升为复旦大学副教授博士生导师，同年5月升任复旦大学教授。曾主讲《现代化学专题－表面化学》、《物理化学》和《催化反应机理》等课程。指导研究生多名，其中3名已获硕士学位。
科研上主要从事表面化学和多相催化研究，涉及高性能新结构纳米介孔催化材料的创制与绿色催化应用、低碳烷烃选择氧化制烯烃、1,3-丙二醇等聚酯原料关键单体的催化加氢合成、金属/半导体光催化、催化过程的原位动态谱学表征及C1资源的综合利用等。最近主持的项目有国家自然科学基金（2项）、上海市科委纳米科技专项、上海市科委科技启明星计划等，并参与了973项目等多项国家级和省部级重大课题研究。2004年，作为研究骨干之一，获国家基金委优秀创新群体基金资助。在新型纳米催化材料的研制及应用、催化原位谱学表征和催化理论的研究方面取得了一定的成果，累计发表论文100余篇，其中在J. Am. Chem. Soc., Angew. Chem., J. Phys. Chem. B., Langmuir, J. Chem. Phys., J. Catal., Chem. Commun., Appl. Catal., Catal. Lett., Catal. Today, Chem. Phys. Lett., New J. Chem.等SCI源刊物上发表论文180余篇；论文被国内外引用3000余次；申请中国发明专利20件（授权专利8件）；参与J. Am. Chem. Soc.、J. Catal.和《高等学校化学学报》、《化学学报》、《物理化学学报》、《石油化工》等刊物的审稿。
荣誉奖励：
1.2014年获得 中国催化青年奖（National Catalysis Prize for Young Scientists）
2.2009年度国家级教学成果二等奖（《微观原理引导的大物理化学课程建设》，范康年，陆靖，唐颐，曹勇，周鸣飞，成果序号：931012）
发展多相催化新技术 创建绿色反应新体系——复旦大学曹勇教授
曹勇教授长期从事多相催化研究，在面向绿色与可持续催化应用的固体催化材料的设计、合成及表征等方面取得了一定的成绩。发展了系列具有“金属”及“表面酸／碱”等多活性位协同集成结构特征的新结构高性能催化材料设计与合成方法，实现了高分散多相金属催化材料微结构及表面特性的精细调控。2001 年至今发表 SCI 论文 160 余篇，其中影响因子大于 3.0 论文 50 余篇，SCI他引3000 余次，10篇论文被他引40次以上，其中单篇最高他引过百次，获得授权中国发明专利20余件。
1．基于小分子协同活化的纳米金催化绿色反应新体系探索
发现并揭示了小尺寸纳米 Au 对于液体甲酸低温催化选择分解的独特催化性能。利用反应耦合与氢转移策略，实现了温和条件下纳米金催化 CO/H2O 选择还原极性不饱和键。揭示并阐明了反应底物与 H2O 及H2等小分子间的协同活化对于温和条件下纳米金催化腈水合以及喹啉高选择性催化加氢制四氢喹啉等反应的重要性。以 O2及 H2O2为清洁氧源，研制出用于醇液相选择氧化的高性能纳米金催化新体系。
（1）以液体甲酸（HCOOH）为可再生能源载体的制氢／储氢研究是当前国际上能源催化领域十分重要的课题。针对传统 Pt 族多相贵金属催化低温液相甲酸分解体系存在的反应效率和选择性偏低及稳定性不足等问题，通过对 Au 纳米颗粒尺寸、催化载体及反应介质等关键参数的系统探究，发现并确立了一类基于“甲酸-三乙胺”为反应介质的可在环境温度下实现甲酸高效选择分解制氢的新型亚纳米 Au/ZrO2催化体系，为认识并理解 Au 对甲酸这一在催化化学研究中最具代表性的“探针分子”的吸附及活化行为提供了新的实践与理论依据。
（2）针对现有金催化还原存在的突出问题，先后采用以异丙醇、甲酸盐等含氢化合物为氢源以及通过与水汽变换（CO + H2O = H2 + CO2）反应进行耦合的氢转移（CTH）策略，成功实现了温和条件下纳米金对硝基、羰基及炔基等系列不饱和官能团的选择可控催化还原。其中以 CO/H2O 为氢源成功实现在室温常压下硝基化合物金催化选择还原的工作被遴选为热点论文（Hot Paper）在Angew. Chem. Int. Ed. 上被予以着重介绍。
（3）在对 Au 催化 CO/H2O 还原硝基的还原机制研究中发现，H2O 解离是反应的速控步骤。受此启发，进而发现负载纳米Au 催化界面处共吸附的腈基团（CN）可显著活化H2O 分子，使得 Au/TiO2可在80 ℃温和条件下高效催化多类有机腈选择水解至相应的酰胺化合物。该发现被列选为ChemSusChem刊物当期封面论文。据此进一步探索研究了 H2与喹啉在纳米 Au 上的“协同活化”行为。H2/D2交换等系列研究表明，含有碱性基团的喹啉在温和条件下可显著促进纳米 Au 对H2的催化活化。由此成功实现了利用TiO2负载Au 催化喹啉选择加氢高选择性高收率制取药物合成中极为重要的四氢喹啉化合物。与同等条件下Pd、Pt 等传统贵金属表现截然不同的是，在该反应中Au 不但未表现出因反应底物强吸附导致的中毒失活现象，反而表现出独特的“底物自促进效应”。
（4）在对以 O2为氧源的醇液相选择氧化研究中，从载体设计与优化入手，以具独特脱氢特性的Ga-Al 复合氧化物为载体获得了高活性的Au/Ga3Al3O9催化剂。与此同时，针对“非活泼”脂肪醇的选择氧化，尝试将H2O2引入纳米金催化醇氧化反应中，发现H2O2-Au/TiO2对于脂肪醇选择氧化特别有效，为纳米金在环境友好选择氧化中的应用开拓了新方向。相关系列论文自 2008 年以来已获包括Chem. Rev.、Chem. Soc. Rev.、Angew. Chem.、J. Am. Chem. Soc.等在内的一流期刊 150 余次引用与评述。
2．涉及多活性位协同集成的多相催化级联反应体系的构建
揭示并阐明了多活性位协同集成及级联反应策略用于调控反应通道及实现高选择性绿色合成的重要性，发展出从醇、硝基化合物等简单原料出发“一步”清洁合成酯、亚胺、仲胺、喹啉及偶氮化合物等精细复杂分子的几类高性能纳米 Au 及Ir基催化反应新体系；以氧化锆为载体制备了同时对甲酸分解制氢与生物基乙酰丙酸的选择还原制γ-戊内酯以及甘油氢解制正丙醇具高活性的新型纳米Au/ZrO2与Ir/ZrO2系列催化剂，在探索将固体催化材料用于生物质原料高值利用方面取得了进展。
（1）尽可能减少复杂精细有机分子合成所需的反应步骤是现代合成化学所面临的重要挑战之一。以“多活性位协同集成”概念为指导可望研制出用于绿色级联合成的高效“多功能”固体催化剂。设计了一类兼具“选择氧化”及“催化缩合”双功能特性的Au/-Ga2O3催化体系，成功实现了醇、醛等化合物温和条件下“一步”法直接选择氧化制取在香料工业中极为重要的芳酯类化合物。基于类似思路，利用兼具酸碱及氧化等“多功能”特性的磷灰石载 Au 催化体系成功实现了亚胺、肟及具生理活性的α-氨基亚磷酸酯类化合物等重要精细中间体的高效、清洁、简约合成，为“多活性位协同集成”策略在药物中间体等复杂精细有机分子绿色合成领域中的应用提供了新范例。
（2）基于有关氧化物载Au催化体系兼具良好“醇脱氢活化”及“转移加氢”性能的发现，在TiO2负载的小尺寸纳米Au（～2 nm）催化剂上实现了计量胺／醇经“脱氢–缩合–加氢”等多级连续步骤的“一步式借氢偶联”高选择性合成仲胺类化合物的反应。最近还进一步实现了以醇为烷基化试剂的纳米Au催化廉价硝基化合物一步N-烷基化高选择性合成仲胺及叔胺等高级胺的反应。采用类似策略，在对以Au为主的催化活性金属的筛选中，发现TiO2负载的亚纳米Ir可直接催化硝基与乙醇等低碳醇高收率直接合成喹啉化合物。在上述发现基础上，最近通过对载体表面酸、碱及Au加氢活性位浓度的精细调控与优化，进一步实现了对芳硝基选择加氢过程反应通道的调控，并实现了以防硝基为原料对液晶、染料及药物合成中重要的偶氮类化合物的直接加氢合成。
“多活性协同位集成”用于高性能固体催化剂设计研究思路对于面向可持续绿色合成的催化体系的创制及发展节能降耗的过程强化技术具重要意义，此方向系列论文已获包括Chem. Rev.和Natutre Chemistry等在内的一流期刊80余次引用与评述。
（3）为应对日益严峻的能源与资源危机，世界各国近年来高度重视可再生的纤维素等生物质资源的开发利用。在发展“不用 H2”的生物质精炼催化新体系研究方面，以 ZrO2负载亚纳米 Au 为催化剂实现了以甲酸为价廉替代氢源选择还原乙酰丙酸制-戊内酯这一重要的可再生高值化学品，解决了长期以来加氢脱氧等关键过程所面临的依赖化石源 H2等问题；在实用可行的生物质精炼催化新体系的创设方面，进一步发展了Cu/ZrO2催化甲酸选择氢解甘油等过程的非贵金属催化体系；在面向可再生大宗化学品合成的非石油基催化路线的设计与构建方面，提出并发展了一条经由正丙醇关键中间体的甘油“选择氢解–脱水”生物质制丙烯增产新技术。
来源：科学成果管理与研究 2015年第8期
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